Homoleptic lanthanide complexes of chelating phosphanamides - An experimental and theoretical study

被引：1

作者：

Wetzel, TG ^{[1
]}

Dehnen, S ^{[1
]}

Roesky, PW ^{[1
]}

机构：

[1] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 08期

关键词：

ab initio calculations; chelates; density functional calculations; lanthanides; phosphanamides;

D O I：

10.1002/(SICI)1521-3773(19990419)38:8<1086::AID-ANIE1086>3.0.CO;2-E

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four chelating ligands are present in the first phosphanamide complexes of Group 3 metals and the lanthanides (see structure shown). However, these ligands coordinate to form a distorted molecular structure. The compounds were characterized by single-crystal X-ray structure analysis and quantum- mechanical investigations with density functional theory and MP2 methods.

引用

页码：1086 / 1088

页数：3

共 50 条

[21] Experimental and Theoretical Studies on the Magnetic Anisotropy in Lanthanide(III)-Centered Fe3Ln Propellers [J].

Rigamonti, Luca ;

Nava, Andrea ;

Boulon, Marie-Emmanuelle ;

Luzon, Javier ;

Sessoli, Roberta ;

Cornia, Andrea .

CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (34) :12171-12180

[22] Vibrational Quenching in Near-Infrared Emitting Lanthanide Complexes: A Quantitative Experimental Study and Novel Insights [J].

Mara, Dimitrije ;

Artizzu, Flavia ;

Smet, Philippe F. ;

Kaczmarek, Anna M. ;

Van Hecke, Kristof ;

Van Deun, Rik .

CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (69) :15944-15956

[23] Potentiometric Study of Lanthanide Salicylaldimine Schiff Base Complexes [J].

Kaczmarek, Malgorzata T. ;

Jastrzab, Renata ;

Radecka-Paryzek, Wanda .

JOURNAL OF SOLUTION CHEMISTRY, 2013, 42 (01) :18-26

[24] Enthalpy/Entropy Compensation in the Melting of Thermotropic Nitrogen-Containing Chelating Ligands and Their Lanthanide Complexes: Successes and Failures [J].

Escande, Aude ;

Guenee, Laure ;

Terazzi, Emmanuel ;

Jensen, Thomas B. ;

Nozary, Homayoun ;

Piguet, Claude .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (18) :2746-2759

[25] Potentiometric Study of Lanthanide Salicylaldimine Schiff Base Complexes [J].

Małgorzata T. Kaczmarek ;

Renata Jastrząb ;

Wanda Radecka-Paryzek .

Journal of Solution Chemistry, 2013, 42 :18-26

[26] A combined experimental and theoretical study of the molecular inclusion of organometallic sandwich complexes in a cavitand receptor [J].

Zuidema, Erik ;

Sarmentero, M. Angeles ;

Bo, Carles ;

Ballester, Pablo .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (24) :7285-7295

[27] Mechanism of the Dehydrogenative Silylation of Alcohols Catalyzed by Cationic Gold Complexes: An Experimental and Theoretical Study [J].

Labouille, Stephanie ;

Escalle-Lewis, Aurelie ;

Jean, Yves ;

Mezailles, Nicolas ;

Le Floch, Pascal .

CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (07) :2256-2265

[28] Mechanistic Aspects of the Gas-Phase Reactions of Halobenzenes with Bare Lanthanide Cations: A Combined Experimental/Theoretical Investigation [J].

Zhou, Shaodong ;

Schlangen, Maria ;

Schwarz, Helmut .

CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (05) :2123-2131

[29] Synthesis and Bonding in Carbene Complexes of an Unsymmetrical Dilithio Methandiide: A Combined Experimental and Theoretical Study [J].

Gessner, Viktoria H. ;

Meier, Florian ;

Uhrich, Diana ;

Kaupp, Martin .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (49) :16729-16739

[30] Assembly of π-Conjugated Phosphole Azahelicene Derivatives into Chiral Coordination Complexes: An Experimental and Theoretical Study [J].

Graule, Sebastien ;

Rudolph, Mark ;

Shen, Wenting ;

Williams, J. A. Gareth ;

Lescop, Christophe ;

Autschbach, Jochen ;

Crassous, Jeanne ;

Reau, Regis .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (20) :5976-6005

← 1 2 3 4 5 →