A Novel and Highly Efficient Photocatalyst Based on P25-Graphdiyne Nanocomposite

被引:301
作者
Wang, Shuo [1 ,2 ]
Yi, Luoxin [1 ]
Halpert, Jonathan E. [1 ]
Lai, Xiaoyong [1 ]
Liu, Yuanyuan [1 ]
Cao, Hongbin [1 ]
Yu, Ranbo [3 ]
Wang, Dan [1 ]
Li, Yuliang [1 ,4 ]
机构
[1] Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
[3] Univ Sci & Technol Beijing, Dept Phys Chem, Beijing 100083, Peoples R China
[4] Chinese Acad Sci, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
graphdiyne; hydrothermal synthesis; nanocomposites; photocatalysis; titania; TITANIUM-DIOXIDE; CARBON NANOTUBES; ELECTRONIC-STRUCTURES; TIO2; COMPOSITE; DEHYDROBENZOANNULENES; DEGRADATION; PERFORMANCE; SURFACE; OXIDATION;
D O I
10.1002/smll.201101686
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Titania nanoparticles (P25) are successfully chemically bonded with graphdiyne (GD) nanosheets by a facile hydrothermal treatment, to form a novel nanocomposite photocatalyst. The as-prepared P25GD nanocomposite exhibits higher photocatalytic activity for degrading methylene blue under UV irradiation than not only P25 and P25carbon nanotube composite but also the current well-known P25graphene composite photocatalysts. Moreover, P25GD also shows considerable visible-light-driven photocatalytic activity, since the formation of chemical bonds between P25 and GD effectively decreases the bandgap of P25 and extends its absorbable light range. The photocatalytic activity of P25GD can be adjusted by changing the content of GD in composites and the optimized value is about 0.6 wt%. Such a nanocomposite photocatalyst might find potential application in a wide range of fields including air purification and waste water treatment.
引用
收藏
页码:265 / 271
页数:7
相关论文
共 47 条
[1]   Photodegradation of Graphene Oxide Sheets by TiO2 Nanoparticles after a Photocatalytic Reduction [J].
Akhavan, O. ;
Abdolahad, M. ;
Esfandiar, A. ;
Mohatashamifar, M. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (30) :12955-12959
[2]   ELECTROABSORPTION IN RUTILE (TIO2) [J].
ARNTZ, F ;
YACOBY, Y .
PHYSICAL REVIEW LETTERS, 1966, 17 (16) :857-&
[3]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[4]   STRUCTURE-PROPERTY PREDICTIONS FOR NEW PLANAR FORMS OF CARBON - LAYERED PHASES CONTAINING SP2 AND SP ATOMS [J].
BAUGHMAN, RH ;
ECKHARDT, H ;
KERTESZ, M .
JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (11) :6687-6699
[5]   Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].
Becerril, Hdctor A. ;
Mao, Jie ;
Liu, Zunfeng ;
Stoltenberg, Randall M. ;
Bao, Zhenan ;
Chen, Yongsheng .
ACS NANO, 2008, 2 (03) :463-470
[6]   Single-walled carbon nanotube scaffolds for dye-sensitized solar cells [J].
Brown, Patrick ;
Takechi, Kensuke ;
Kamat, Prashant V. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (12) :4776-4782
[7]   The effect of graphdiyne doping on the performance of polymer solar cells [J].
Du, Hailiang ;
Deng, Zhenbo ;
Lu, Zhaoyue ;
Yin, Yuehong ;
Yu, LingLing ;
Wu, Hui ;
Chen, Zheng ;
Zou, Ye ;
Wang, Yongsheng ;
Liu, Huibiao ;
Li, Yuliang .
SYNTHETIC METALS, 2011, 161 (19-20) :2055-2057
[8]   Hierarchically Ordered Macro-Mesoporous TiO2-Graphene Composite Films: Improved Mass Transfer, Reduced Charge Recombination, and Their Enhanced Photocatalytic Activities [J].
Du, Jiang ;
Lai, Xiaoyong ;
Yang, Nailiang ;
Zhai, Jin ;
Kisailus, David ;
Su, Fabing ;
Wang, Dan ;
Jiang, Lei .
ACS NANO, 2011, 5 (01) :590-596
[9]   Tantalum-Doped Titanium Dioxide Nanowire Arrays for Dye-Sensitized Solar Cells with High Open-Circuit Voltage [J].
Feng, Xinjian ;
Shankar, Karthik ;
Paulose, Maggie ;
Grimes, Craig A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (43) :8095-8098
[10]   HETEROGENEOUS PHOTOCATALYTIC OXIDATION OF AROMATIC-COMPOUNDS ON TIO2 [J].
FUJIHIRA, M ;
SATOH, Y ;
OSA, T .
NATURE, 1981, 293 (5829) :206-208