Oxidation of Propylene with Oxygen and Air in a Barrier Discharge in the Presence of Octane

被引：14

作者：

Kudryashov, Sergey ^{[1
]}

Ochered'ko, Andrey ^{[1
]}

Ryabov, Andrey ^{[1
]}

Shchyogoleva, Galina ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petr Chem, Siberian Branch, Tomsk, Russia

来源：

PLASMA CHEMISTRY AND PLASMA PROCESSING | 2011年 / 31卷 / 05期

关键词：

Barrier discharge; Oxidation; Propylene; Propylene oxide; Octane; EPOXIDATION; CATALYSTS; O(P-3); ATOMS;

D O I：

10.1007/s11090-011-9318-z

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Oxidation of propylene with oxygen, air and a mixture of nitrogen-oxygen in a barrier discharge is investigated. The selectivity towards formation of propylene oxide in pure oxygen is shown to be as high as 45 wt% and the propylene conversion ratio is found to be 12.9 wt%. In the oxidation with air, the propylene oxide selectivity is 23 wt%, while the conversion is 7.5 wt%. The values of propylene conversion and selectivity towards formation of propylene oxide in a barrier discharge are consistent with those obtained by the thermocatalytic methods for production of propylene oxide.

引用

页码：649 / 661

页数：13

共 19 条

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