Metal array fabrication through self-assembly of Pt-complex-bound amino acids

被引：19

作者：

Isozaki, Katsuhiro ^{[1
,2
,3
]}

Ogata, Kazuki ^{[3
,4
]}

Haga, Yusuke ^{[1
]}

Sasano, Daisuke ^{[3
,4
]}

Ogawa, Tetsuya

Kurata, Hiroki

Nakamura, Masaharu ^{[3
,4
]}

Naota, Takeshi ^{[1
]}

Takaya, Hikaru ^{[1
,3
,4
,5
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan

[2] Natl Inst Mat Sci, Polymer Mat Unit, Tsukuba, Ibaraki 3050044, Japan

[3] Kyoto Univ, Inst Chem Res, Int Res Ctr Elements Sci, Uji, Kyoto 6110011, Japan

[4] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Uji, Kyoto 6110011, Japan

[5] Japan Sci & Technol Agcy, PRESTO, Tokyo, Japan

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 33期

基金：

日本科学技术振兴机构;

关键词：

CHAIN PLEATED SHEET; AMIDE-ONE VIBRATION; INFRARED-SPECTRA; ORGANIC FLUIDS; RESONANCE INTERACTION; INSTANT GELATION; PEPTIDES; GELATORS; DESTRUCTION; TRANSITION;

D O I：

10.1039/c2cc17530d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new type of Pt-complex-bound amino acid was synthesized by condensation of a cyclometalated Pt complex with the side-chain residue of N- and C-alkylated glutamic acid. Self-assembly of the Pt-bound lipophilic amino acid afforded a supramolecular gel in organic solvents, which comprised fibrous lamellar aggregates that supported a highly oriented Pt array.

引用

页码：3936 / 3938

页数：3

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