The role of pH in the density control of ferritin-based catalyst nanoparticles towards scalable single-walled carbon nanotube growth

被引:10
作者
Chikkadi, Kiran [1 ]
Mattmann, Moritz [1 ]
Muoth, Matthias [1 ]
Durrer, Lukas [1 ]
Hierold, Christofer [1 ]
机构
[1] ETH, Dept Mech & Proc Engn, CH-8092 Zurich, Switzerland
基金
瑞士国家科学基金会;
关键词
Catalyst; Ferritin; pH; Single-walled; Carbon nanotube; Growth; Scalability; Nanoparticle;
D O I
10.1016/j.mee.2011.02.069
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
We present a study on the influence of pH in the control of the surface density of ferritin-based iron oxide nanoparticles. It is found that at pH 3, the adsorption coverage of ferritin on the substrate is more than 1000 particles/mu m(2), owing to coulombic attraction between ferritin and the substrate. Upon increasing the pH to 9 and reducing the concentration, the surface density is reduced to as low as 2 particles/mu m(2), owing to coulombic repulsion. The average particle size is unaffected by the pH change. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:2478 / 2480
页数:3
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