Facile Synthesis and Characterization of Fe/FeS Nanoparticles for Environmental Applications

被引:387
作者
Kim, Eun-Ju [1 ]
Kim, Jae-Hwan [1 ]
Azad, Abdul-Majeed [2 ]
Chang, Yoon-Seok [1 ]
机构
[1] Pohang Univ Sci & Technol POSTECH, Sch Environm Sci & Engn, Pohang 790784, South Korea
[2] Univ Toledo, Dept Chem Engn, Toledo, OH 43606 USA
关键词
multicomponent nanoparticles; dithionite; iron sulfides; zerovalent iron; TCE; ZERO-VALENT IRON; SULFIDE; TRICHLOROETHYLENE; DECHLORINATION; REDUCTION; KINETICS; TRANSFORMATION; NANOCOMPOSITE; DITHIONITE; PARTICLES;
D O I
10.1021/am200016v
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Multicomponent nanoparticles containing two or more different types of functionalities show unique physical and chemical properties, leading to significantly enhanced performance. In this study, we have developed a new one-pot method to prepare Fe/FeS nanoparticles using dithionite at room temperature. The FeS precipitates on the Fe surface are formed by the interaction between dissolved iron species and hydrogen, sulfide, one of the decomposition products of dithionite in solution. The resulting Fe/FeS nanopartides have high surface area, good electrical conductivity, and strong magnetic responsivity. In addition, the Fe/FeS shows a much higher reactivity toward contaminants than the pure Fe nanoparticles. The above synthesized nanoparticles are successfully applied for the rapid removal of trichloroethylene (TCE) from water. The study reveals that Fe/FeS nanoparticles are a promising candidate for the efficient removal of pollutants.
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页码:1457 / 1462
页数:6
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