Nanofocusing, shadowing, and electron mean free path in the photoemission from aerosol droplets

被引：69

作者：

Signorell, Ruth ^{[1
]}

Goldmann, Maximilian ^{[1
]}

Yoder, Bruce L. ^{[1
]}

Bodi, Andras ^{[2
]}

Chasovskikh, Egor ^{[1
]}

Lang, Lukas ^{[1
]}

Luckhaus, David ^{[1
]}

机构：

[1] ETH, Phys Chem Lab, Dept Chem & Appl Biosci, Vladimir Prelog Weg 2, CH-8093 Zurich, Switzerland

[2] Paul Scherrer Inst, CH-5232 Villigen, Switzerland

来源：

CHEMICAL PHYSICS LETTERS | 2016年 / 658卷

基金：

瑞士国家科学基金会;

关键词：

Solvated electron; Water; Electron attenuation length; Photoelectron angular distribution; Velocity map imaging; PHOTOELECTRON-SPECTROSCOPY; SOLVATED ELECTRONS; LIQUID WATER; NACL NANOPARTICLES; CROSS-SECTIONS; NANOSPHERES; SCATTERING; PARTICLES; INTERFACE; RADIATION;

D O I：

10.1016/j.cplett.2016.05.046

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Angle-resolved photoelectron spectroscopy of aerosol droplets is a promising method for the determination of electron mean free paths in liquids. It is particularly attractive for volatile liquids, such as water. Here we report the first angle-resolved photoelectron images of droplets with defined sizes, viz. of water, glycerol, and dioctyl phthalate droplets. Simulations of water droplet photoelectron images and data for electron mean free paths for liquid water at low kinetic energy (<3 eV) are provided. We present an approach that allows one to gradually vary the conditions from shadowing to nanofocusing to optimize the information content contained in the photoelectron images. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：1 / 6

页数：6

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