μ-2,2′,6,6′-Tetramethyl-4,4′-bipyridine-κ2N1:N1′-bis[(diethylenetriamine-κ3N,N′,N")palladium(II)] tetranitrate

被引：1
|
作者：
Seidel, Ruediger W. [1 ]
Oppel, Iris M. [2 ]
机构：
[1] Lehrstuhl Analyt Chem, D-44780 Bochum, Germany
[2] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52074 Aachen, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2011年 / 67卷
关键词：
PILLARED COORDINATION CAGES; DISCRETE STACKING; COMPLEXES; 4,4'-BIPYRIDINE; SUBSTITUTION; MOLECULES; PD;
D O I：
10.1107/S0108270111017586
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Pd-2(C4H13N3)(2)(C14H16N2)](NO3)(4), comprises discrete tetracationic dumbbell-type dinuclear complex molecules and noncoordinating nitrate anions. Two Pd(dien)(2+) moieties (dien is diethylenetriamine) are joined by the rigid linear exo-bidentate bridging 2,2',6,6'-tetramethyl-4,4'-bipyridine ligand to form the dinuclear complex, which lies across a centre of inversion in the space group P2(1)/n, so that the rings in the 2,2',6,6'-tetramethyl-4,4'-bipyridine bridging ligand are parallel. In the crystal, the primary and secondary amino groups of the dien ligand act as hydrogen-bond donors towards the nitrate anions to form a three-dimensional hydrogen-bond network.
引用
收藏
页码：M199 / M201
页数：3
相关论文
共 50 条
  • [1] Dichlorido(6,6'-dimethyl-2,2'-bipyridine-κ2 N,N')cadmium(II)
    Alizadeh, Robabeh
    Eshlaghi, Parisa Mohammadi
    Amani, Vahid
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1024 - U1496
  • [2] (6,6′-Dimethyl-2,2′-bipyridine-κ2N,N′)diiodidomercury(II)
    Alizadeh, Robabeh
    Seifi, Sara
    Amani, Vahid
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M305 - U242
  • [3] Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ2N,N′)zinc(II)
    Alizadeh, Robabeh
    Kalateh, Khadijeh
    Ebadi, Amin
    Ahmadi, Roya
    Amani, Vahid
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1250 - +
  • [4] Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ2N,N′)cobalt(II)
    Torbati, Niloufar Akbarzadeh
    Rezvani, Ali Reza
    Safari, Nasser
    Saravani, Hamideh
    Amani, Vahid
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1284 - U1070
  • [5] (2,2′-Bipyridine-κ2N,N′)chlorido[4′-(2,5-dimethoxyphenyl)-2,2′:6′,2"-terpyridine-κ3N,N′,N"]ruthenium(II) hexafluoridophosphate acetonitrile monosolvate
    Oyama, Dai
    Kido, Masato
    Orita, Ai
    Takase, Tsugiko
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1117 - U942
  • [6] Dibromido(4,4'-dimethyl-2,2'-bipyridine-κ2 N,N')zinc(II)
    Alizadeh, Robabeh
    Eshlaghi, Parisa Mohammadi
    Amani, Vahid
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M996 - U1253
  • [7] Aqua[2-(2-pyridyl)-1,8-naphthyridine-κ2N1,N2](2,2′:6′,2"-terpyridine-κ3N,N′,N")ruthenium(II) bis(hexafluoridophosphate) acetone sesquisolvate
    Oyama, Dai
    Yuzuriya, Kazumi
    Takase, Tsugiko
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M737 - U908
  • [8] (2,2′-Bipyridine-4,4′-dicarboxylic acid-κ2N,N′)chlorido(2,2′:6′,2"-terpyridyl-κ3N,N′,N")ruthenium(II) perchlorate ethanol monosolvate monohydrate
    Nielsen, Anne
    McKenzie, Christine J.
    Bond, Andrew D.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : M77 - +
  • [9] Dibromido(6-methyl-2,2′-bipyridine-κ2N,N′)zinc(II)
    Kalateh, Khadijeh
    Ahmadi, Roya
    Amani, Vahid
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1241 - U670
  • [10] Dimethyl(2,2′:6′,2"-terpyridine-κ3N,N′,N")zinc(II)
    Shalumova, Tamila
    Tanski, Joseph M.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1325 - U786
12345