Oxidation of Acetic Acid by Hydrogen Peroxide in the Aqueous Medium in Supercritical Fluid Conditions

被引：3

作者：

Mazanov, S. V. ^{[1
]}

Aetov, A. U. ^{[1
]}

Usmanov, R. A. ^{[1
]}

Gabitov, R. R. ^{[1
]}

Zaripov, Z. I. ^{[1
]}

Gumerov, F. M. ^{[1
]}

机构：

[1] Kazan Natl Res Technol Univ, Kazan 420015, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B | 2019年 / 13卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

supercritical water oxidation; acetic acid; pH; oxygen chemical consumption index;

D O I：

10.1134/S1990793119070194

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The oxidation of acetic acid (AA) in its 10% aqueous solution at 673-748 K and 25 MPa is studied in periodic and continuous regimes. Hydrogen peroxide is used as an oxidant. The degree of AA conversion is determined based on the oxygen chemical consumption index.

引用

页码：1131 / 1134

页数：4

共 23 条

[1]

Aetov A U, 2016, VESTN KAZAN TEKHNOL, V19, P37

[2]

Alekseev S. E., 2006, THESIS

[3] LUMPING STRATEGY FOR MODELING THE OXIDATION OF C1-C3 ALCOHOLS AND ACETIC-ACID IN HIGH-TEMPERATURE WATER [J].