Solar fuels via chemical-looping reforming

被引:61
作者
Krenzke, Peter T. [1 ]
Fosheim, Jesse R. [2 ]
Davidson, Jane H. [2 ]
机构
[1] Taylor Univ, Phys & Engn Dept, 236 W Reade Ave, Upland, IN 46989 USA
[2] Univ Minnesota, Dept Mech Engn, 111 Church St SE, Minneapolis, MN 55455 USA
基金
美国国家科学基金会;
关键词
Fuel; Solar thermochemical; Metal oxide; Reforming; METHANE PARTIAL OXIDATION; THERMOCHEMICAL HYDROGEN-PRODUCTION; PEROVSKITE-TYPE OXIDES; OXYGEN-CARRIER MATERIALS; MACROPOROUS LAFEO3 PEROVSKITES; LANTHANUM-BASED PEROVSKITE; WATER-SPLITTING REACTION; SYNTHESIS GAS GENERATION; CEO2-ZRO2; SOLID-SOLUTION; COMBINED ZNO-REDUCTION;
D O I
10.1016/j.solener.2017.05.095
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The potential of solar thermal chemical-looping reforming for efficient and sustainable co-production of synthesis gas and hydrogen is discussed. In an endothermic partial oxidation step, methane reacts with oxygen released from a metal oxide to produce hydrogen and carbon monoxide. In an exothermic second step, steam reacts with the reduced metal oxide to produce hydrogen. This review summarizes the process and chemical thermodynamic foundations of solar chemical-looping reforming and provides a synopsis of materials studies that reflect the state of knowledge in 2017. The challenges and opportunities for future research and development are discussed. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:48 / 72
页数:25
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