The journey of C-S bond formation from metal catalysis to electrocatalysis

被引:9
作者
Chen, Ze-Wei [1 ]
Bai, Rekha [1 ,2 ]
Annamalai, Pratheepkumar [1 ]
Badsara, Satpal Singh [2 ]
Lee, Chin-Fa [1 ,3 ,4 ]
机构
[1] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan
[2] Univ Rajasthan, Dept Chem, MFOS Lab, Jaipur 302004, Rajasthan, India
[3] Natl Chung Hsing Univ, ICtr Adv Sci & Technol iCAST, Taichung 402, Taiwan
[4] Natl Chung Hsing Univ, Innovat & Dev Ctr Sustainable Agr IDCSA, Taichung 402, Taiwan
关键词
CROSS-COUPLING REACTION; ARYL HALIDES; TRANSITION-METAL; DIARYL SULFIDES; H FUNCTIONALIZATION; MEDIATED SYNTHESIS; BORONIC ACIDS; THIOLS; COPPER; THIOESTERS;
D O I
10.1039/d1nj04662d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Due to widespread applications of sulfur-containing frameworks, the construction of the C-S bond has emerged as a useful tool for synthetic organic and medicinal chemists in the recent years. Initially, the C-S bond formations were carried out under transition metal catalysis. The last 10-15 years have been a glorified era for the C-S bond constructions during which various sustainable procedures have been developed. This perspective describes the journey of C-S bond construction starting from transition metal catalysis through oxidant catalysis, photocatalysis and the very recently employed electrocatalysis using various sulfur surrogates.
引用
收藏
页码:15 / 38
页数:24
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