In situ Ge-Ge bond formation under ambient conditions: synthesis, characterization and reactivity of organo-functionalized telluridogermanate complexes

被引：26
作者：
Heimann, Samuel
Holynska, Malgorzata
Dehnen, Stefanie [1 ]
机构：
[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 06期
关键词：
RAY STRUCTURAL-ANALYSIS; TETRA(METHYLGERMANIUM) HEXASULFIDE; CRYSTAL-STRUCTURES; GERMANIUM; ADAMANTANE; CHALCOGENIDES; DERIVATIVES; SILICON; CLUSTER; SE;
D O I：
10.1039/c0cc03727c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Unprecedented noradamantane-type compounds [((RGe)-Ge-2,3)(4)Te-5] (R-2 = CH2CH2COOH, R-3 = CH(CH2COOH)(2)), containing a Ge-Ge bond, yield from reactions of (RGeCl3)-Ge-2,3 with Na2Te or Li2Te in THF, while reactions with (RGeCl3)-Ge-1 (R-1 = CMe2CH2COMe) afford a double-decker-type cage [((RGe)-Ge-3)(4)Te-6]; by reaction with hydrazine, the latter reacts to the hydrazone functionalized, monomeric anion [((RGe)-Ge-4)Te-2](-) (R-4 = CMe2CH2CNNH2Me).
引用
收藏
页码：1881 / 1883
页数：3
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