Synthesis, structure, and properties of a novel hydrated borate Rb4[B4O5(OH)4]2•3H2O

被引：11

作者：

Zhao, Yi ^{[1
,2
]}

Pan, Shilie ^{[1
]}

Li, Feng ^{[1
]}

Wang, Yongjiang ^{[1
]}

Fan, Xiaoyun ^{[1
]}

Dong, Xiaoyu ^{[1
]}

Jia, Dianzeng ^{[2
]}

Guo, Jixi ^{[2
]}

Zhou, Zhongxiang ^{[1
]}

机构：

[1] Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China

[2] Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China

来源：

SOLID STATE SCIENCES | 2011年 / 13卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Rb-4[B4O5(OH)(4)](2)center dot 3H(2)O; Borate; Crystal structure; Crystal growth; NONLINEAR-OPTICAL CRYSTAL; THERMAL-BEHAVIOR; RUBIDIUM PENTABORATE; GROWTH; TETRAHYDRATE; REFINEMENT; CS; RB; TL;

D O I：

10.1016/j.solidstatesciences.2010.10.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rb-4[B4O5(OH)(4)]2 center dot 3H(2)O has been grown by slow evaporation method with crystal sizes up to 11 mm x 7 mm x 4 mm. Its crystal structure has been determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (XRD). IR, and TGA. It crystallizes in the orthorhombic space group Pbcn, with a = 16.3984(14) angstrom, b = 7.7850(7) angstrom, c = 16.0763(16) angstrom, and Z = 4. It contains isolated [B4O5(OH)(4)](2-) polyanions, free water molecules and Rb cations. The Rb(1) and Rb(2) atoms are coordinated by nine and ten oxygen atoms, respectively. Connections between isolated [B4O5(OH)(4)](2-) polyanions are provided by Rb polyhedra and the hydrogen-bonding to form a three-dimensional network. (C) 2010 Elsevier Masson SAS. All rights reserved.

引用

页码：82 / 87

页数：6

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