Synthesis, structure, and properties of a novel hydrated borate Rb4[B4O5(OH)4]2•3H2O

被引：11
|
作者：
Zhao, Yi [1 ,2 ]
Pan, Shilie [1 ]
Li, Feng [1 ]
Wang, Yongjiang [1 ]
Fan, Xiaoyun [1 ]
Dong, Xiaoyu [1 ]
Jia, Dianzeng [2 ]
Guo, Jixi [2 ]
Zhou, Zhongxiang [1 ]
机构：
[1] Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
[2] Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
来源：
SOLID STATE SCIENCES | 2011年 / 13卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Rb-4[B4O5(OH)(4)](2)center dot 3H(2)O; Borate; Crystal structure; Crystal growth; NONLINEAR-OPTICAL CRYSTAL; THERMAL-BEHAVIOR; RUBIDIUM PENTABORATE; GROWTH; TETRAHYDRATE; REFINEMENT; CS; RB; TL;
D O I：
10.1016/j.solidstatesciences.2010.10.013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Rb-4[B4O5(OH)(4)]2 center dot 3H(2)O has been grown by slow evaporation method with crystal sizes up to 11 mm x 7 mm x 4 mm. Its crystal structure has been determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (XRD). IR, and TGA. It crystallizes in the orthorhombic space group Pbcn, with a = 16.3984(14) angstrom, b = 7.7850(7) angstrom, c = 16.0763(16) angstrom, and Z = 4. It contains isolated [B4O5(OH)(4)](2-) polyanions, free water molecules and Rb cations. The Rb(1) and Rb(2) atoms are coordinated by nine and ten oxygen atoms, respectively. Connections between isolated [B4O5(OH)(4)](2-) polyanions are provided by Rb polyhedra and the hydrogen-bonding to form a three-dimensional network. (C) 2010 Elsevier Masson SAS. All rights reserved.
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收藏
页码：82 / 87
页数：6
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