Fourfold Suzuki-Miyaura and Sonogashira Cross-Coupling Reactions on Tetrahedral Methane and Adamantane Derivatives

被引：26
|
作者：
Schilling, Christine I. [1 ,2 ]
Plietzsch, Oliver [1 ,2 ]
Nieger, Martin [3 ]
Muller, Thierry [1 ,2 ]
Braese, Stefan [1 ,2 ]
机构：
[1] Karlsruhe Inst Technol KIT, Inst Organ Chem, D-76131 Karlsruhe, Germany
[2] Karlsruhe Inst Technol KIT, Ctr Funct Nanostruct CFN, D-76131 Karlsruhe, Germany
[3] Univ Helsinki, Inorgan Chem Lab, FIN-00014 Helsinki, Finland
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 2011卷 / 09期
关键词：
Cross-coupling; Hydrocarbons; Adamantane; Organic building unit; Molecular tecton; METAL-ORGANIC FRAMEWORKS; POLYPHENYLENE DENDRIMERS; 1,3,5,7-TETRASUBSTITUTED ADAMANTANES; MOLECULAR TECTONICS; CRYSTAL-STRUCTURES; POLYMER NETWORKS; DIAMONDOID NETS; TETRAPHENYLMETHANE; DESIGN; MORPHOLOGY;
D O I：
10.1002/ejoc.201001567
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient way to generate a series of rigid tetrahedral organic building units from common methane and adamantane precursors is presented. Suzuki-Miyaura and Sonogashira cross-coupling reactions are used to effectively generate these shape-persistent molecular tectons. Especially the Sonogashira reactions employing the readily available tetrahedral alkynes and commercial iodides and bromides are very effective.
引用
收藏
页码：1743 / 1754
页数：12
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