cyclo-Ti3[η2(μ2-C,O)]3:: a side-on-bonded polycarbonyl titanium cluster with potentially antiaromatic character

被引：64

作者：

Xu, Q ^{[1
]}

Jiang, L

Tsumori, N

机构：

[1] AIST, Ikeda, Osaka 5638577, Japan

[2] Kobe Univ, Grad Sch Sci & Technol, Nada Ku, Kobe, Hyogo 6578501, Japan

[3] Toyama Natl Coll Technol, Toyama 9398630, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 28期

关键词：

antiaromaticity; cluster compounds; density functional calculations; IR spectroscopy; matrix isolation;

D O I：

10.1002/anie.200500364

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A windmill-like trititanium cluster with side-on-bonded CO ligands (see picture), which may have antiaromatic character, was revealed by FTIR spectroscopy and DFT calculations. It is generated, along with other side-on-bonded mono- and polycarbonyl di- and trititanium clusters, in the reaction of laser-ablated Ti atoms with CO in a solid argon matrix. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：4338 / 4342

页数：5

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