Raman OD stretching spectral differences between aqueous and alcoholic tetraalkylammonium chloride solutions

被引：7

作者：

Hidaka, F ^{[1
]}

Kanno, H ^{[1
]}

机构：

[1] Natl Def Acad, Dept Appl Chem, Yokosuka, Kanagawa 2398686, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 379卷 / 3-4期

关键词：

D O I：

10.1016/j.cplett.2003.08.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Raman OD stretching spectra were measured for aqueous and alcoholic R4NCl solutions in both liquid state at room temperature and glassy state at liquid nitrogen temperature (alcohol = methanol and ethanol, R = alkyl group: methyl, ethyl and n-propyl). Comparison of the spectra indicates that enhancement of the low frequency region is more pronounced for the glassy aqueous solution than the corresponding alcohol solution. It is suggested that hydrophobic hydration plays a role in the strengthening of hydrogen bonds around an apolar solute (group) at low temperatures in aqueous solution system. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：216 / 222

页数：7

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