CRYSTAL STRUCTURE AND FLUORESCENCE OF A NEW 2D LAYERED CADMIUM(II) MALATE COORDINATION POLYMER

被引：1

作者：

Cui, G. ^{[1
]}

Dong, G. ^{[1
]}

Liu, X. ^{[1
]}

Yu, Ya. ^{[1
]}

机构：

[1] Hebei Polytech Univ, Coll Chem Engn & Biotechnol, Tangshan 063009, Hebei Province, Peoples R China

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 51卷 / 06期

关键词：

cadmium(II); crystal structure; malate ligand; coordination polymer; two-dimension; fluorescence; METAL-ORGANIC FRAMEWORK; MAGNETIC-PROPERTIES; COMPLEXES; HYDRATE; LIGANDS;

D O I：

10.1007/s10947-010-0180-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new two-dimensional layered cadmium coordination polymer [Cd(D,L-mal)H(2)O]n (H(2)mal = malic acid) is solvothermally synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. Each Cd(II) centre is surrounded by seven oxygen atoms from three different malate ligands and one coordinated water molecular forming a pentagonal bipyramidal configuration. Furthermore, complex 1 exhibits blue intense photoluminescence property at room temperature.

引用

页码：1195 / 1200

页数：6

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