CRYSTAL STRUCTURE AND FLUORESCENCE OF A NEW 2D LAYERED CADMIUM(II) MALATE COORDINATION POLYMER

被引：1
|
作者：
Cui, G. [1 ]
Dong, G. [1 ]
Liu, X. [1 ]
Yu, Ya. [1 ]
机构：
[1] Hebei Polytech Univ, Coll Chem Engn & Biotechnol, Tangshan 063009, Hebei Province, Peoples R China
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 51卷 / 06期
关键词：
cadmium(II); crystal structure; malate ligand; coordination polymer; two-dimension; fluorescence; METAL-ORGANIC FRAMEWORK; MAGNETIC-PROPERTIES; COMPLEXES; HYDRATE; LIGANDS;
D O I：
10.1007/s10947-010-0180-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new two-dimensional layered cadmium coordination polymer [Cd(D,L-mal)H(2)O]n (H(2)mal = malic acid) is solvothermally synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. Each Cd(II) centre is surrounded by seven oxygen atoms from three different malate ligands and one coordinated water molecular forming a pentagonal bipyramidal configuration. Furthermore, complex 1 exhibits blue intense photoluminescence property at room temperature.
引用
收藏
页码：1195 / 1200
页数：6
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