Structural characterization of a new copper(II) complex of 1,10-phenanthroline and benzoate [Cu(phen)(C6H5CO 2 - )2]

被引：20

作者：

Batool, S. S. ^{[1
]}

Ahmad, S. ^{[1
]}

Khan, I. U. ^{[2
]}

Ejaz ^{[2
]}

Harrison, W. T. A. ^{[3
]}

机构：

[1] Univ Engn & Technol, Dept Chem, Lahore, Pakistan

[2] Govt Coll Univ, Dept Chem, Lahore, Pakistan

[3] Univ Aberdeen, Dept Chem, Aberdeen, Scotland

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 56卷 / 02期

关键词：

copper(II) carboxylates; 1; 10-phenanthroline; benzoic acid; RAY CRYSTAL-STRUCTURES; MAGNETIC-PROPERTIES; SUPEROXIDE-DISMUTASE; DNA CLEAVAGE; ACID; LIGANDS; BENZIMIDAZOLE; COORDINATION; BIOCHEMISTRY; MONOHYDRATE;

D O I：

10.1134/S0022476615020286

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new mixed-ligand copper(II) complex of 1,10-phenanthroline (phen) and benzoate ligands having the general formula [Cu(phen)(C6H5CO2)(2)] is prepared and its crystal structure is determined by X-ray crystallography. The complex exists in the monomeric form; the coordination environment around the copper(II) ion is square planar, with the pair of monodentate benzoate ligands being in a cis disposition. In the crystal, the molecules are linked into [001] chains by weak C-Ha <-O interactions; no aromatic pi-pi stacking occurs.

引用

收藏

页码：387 / 391

页数：5

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