Structural characterization of a new copper(II) complex of 1,10-phenanthroline and benzoate [Cu(phen)(C6H5CO 2 - )2]

被引：20
作者：
Batool, S. S. [1 ]
Ahmad, S. [1 ]
Khan, I. U. [2 ]
Ejaz [2 ]
Harrison, W. T. A. [3 ]
机构：
[1] Univ Engn & Technol, Dept Chem, Lahore, Pakistan
[2] Govt Coll Univ, Dept Chem, Lahore, Pakistan
[3] Univ Aberdeen, Dept Chem, Aberdeen, Scotland
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 56卷 / 02期
关键词：
copper(II) carboxylates; 1; 10-phenanthroline; benzoic acid; RAY CRYSTAL-STRUCTURES; MAGNETIC-PROPERTIES; SUPEROXIDE-DISMUTASE; DNA CLEAVAGE; ACID; LIGANDS; BENZIMIDAZOLE; COORDINATION; BIOCHEMISTRY; MONOHYDRATE;
D O I：
10.1134/S0022476615020286
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new mixed-ligand copper(II) complex of 1,10-phenanthroline (phen) and benzoate ligands having the general formula [Cu(phen)(C6H5CO2)(2)] is prepared and its crystal structure is determined by X-ray crystallography. The complex exists in the monomeric form; the coordination environment around the copper(II) ion is square planar, with the pair of monodentate benzoate ligands being in a cis disposition. In the crystal, the molecules are linked into [001] chains by weak C-Ha <-O interactions; no aromatic pi-pi stacking occurs.
引用
收藏
页码：387 / 391
页数：5
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