Organic-inorganic hybrid materials derived from epoxy resin and polysiloxanes: Synthesis and characterization

被引：27

作者：

Canto, C. F. ^{[1
]}

Prado, L. A. S. de A. ^{[1
]}

Radovanovic, E. ^{[1
]}

Yoshida, I. V. P. ^{[1
]}

机构：

[1] Univ Estadual Campinas, Inst Quim, BR-13084971 Sao Paulo, Brazil

来源：

POLYMER ENGINEERING AND SCIENCE | 2008年 / 48卷 / 01期

关键词：

D O I：

10.1002/pen.20931

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

In this study, hybrid materials based on epoxy resin were prepared as transparent self-supported films by a sol-gel process. 4,4'-Diaminodiphenylmethane or oligomeric epoxy resin were used as precursors, which were conveniently functionalized with trialkoxysilanes as end-groups. The effect of the introduction of poly (dimethylsiloxane) was also investigated. The hybrid films showed good thermal stability, a nondefined glass transition temperature, and a dense morphology without phase segregation. The tendency to a flat surface could be observed by atomic force microscopy. The hybrid films also showed good performance as coatings for glass plates, with an improved hydrophobic character in comparison to neat epoxy resin.

引用

页码：141 / 148

页数：8

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