The road to early-transition-metal phosphinimide olefin polymerization catalysts

被引：167
|
作者：
Stephan, DW [1 ]
机构：
[1] Univ Windsor, Windsor, ON N9B 3P4, Canada
来源：
ORGANOMETALLICS | 2005年 / 24卷 / 11期
关键词：
D O I：
10.1021/om050096b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This paper chronicles our work examining early-transition-metal systems incorporating phosphinimide ligands for use as olefin polymerization catalysts. Incorporation of these ancillary ligands affords unique deactivation pathways which are readily overcome by specific activation procedures and contrived ligand modification. In these ways, a new family of highly active olefin polymerization catalysts was successfully developed.
引用
收藏
页码：2548 / 2560
页数：13
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