Highly enantioselective hydrogenation of enamides catalyzed by rhodium-monodentate phosphoramidite complex derived from H8-BINOL

被引：32

作者：

Li, XS

Jia, X

Lu, G

Au-Yeung, TTL

Lam, KH

Lo, TWH

Chan, ASC ^{[1
]}

机构：

[1] Hong Kong Polytech Univ, Inst Mol Technol Drug Discovery & Synth, Open Lab Chirotechnol, Hong Kong, Hong Kong, Peoples R China

[2] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China

[3] SW Nationality Coll, Dept Chem, Chengdu, Peoples R China

来源：

TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 18期

关键词：

D O I：

10.1016/j.tetasy.2003.07.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of monodentate phosphoramidite ligands derived from H-8-BINOL have been synthesized. The ligands are used in the Rh-catalyzed asymmetric hydrogenation of enamides to give the acetamides in up to 99% ee. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：2687 / 2691

页数：5

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