Practical and efficient synthesis of C2 symmetrical diamines with Zn/Me3SiCl

被引:0
|
作者
Alexakis, A [1 ]
Aujard, I [1 ]
Mangeney, P [1 ]
机构
[1] Univ Paris 06, Dept Organ Chem, F-75005 Paris, France
关键词
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
C-2 symmetrical diamines are efficiently obtained by reductive coupling of imines with the couple Zn/Me3SiCl. This high yielding method is very practical and cheap for large scale preparation.
引用
收藏
页码:873 / +
页数:3
相关论文
共 50 条
  • [41] Practical Organocatalytic Synthesis of Functionalized Non-C2-Symmetrical Atropisomeric Biaryls
    Gao, Hongyin
    Xu, Qing-Long
    Keene, Craig
    Yousufuddin, Muhammed
    Ess, Daniel H.
    Kuerti, Laszlo
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (02) : 566 - 571
  • [42] Selective derivatizations of resorcarenes.: 4.: General methods for the synthesis of C2ν-symmetrical derivatives
    Shivanyuk, A
    Paulus, EF
    Böhmer, V
    Vogt, W
    JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (19): : 6448 - 6449
  • [43] Synthesis of new C2 symmetrical dibenzospirodiamide and dibenzospirodiamine as potential chiral auxiliaries and building blocks of ionophores
    Choi, HJ
    Park, YJ
    Kim, MG
    Park, YS
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2000, 37 (05) : 1305 - 1308
  • [44] A facile method for synthesis of alkyl phenyl selenides.: The reaction of diphenyl diselenide with oxygen-containing compounds using La/Me3SiCl/cat.I2/cat.CuI system
    Nishino, T
    Nishiyama, Y
    Sonoda, N
    CHEMISTRY LETTERS, 2003, 32 (10) : 918 - 919
  • [45] MODULATION OF C2 SYNTHESIS BY FC AND C3B RECEPTORS
    MCPHADDEN, AR
    WHALEY, K
    JOURNAL OF PATHOLOGY, 1981, 134 (04): : 297 - 298
  • [46] A novel and efficient synthesis of chiral C2-symmetric 1,4-diamines
    Xu, Lianhong
    Desai, Manoj C.
    Liu, Hongtao
    TETRAHEDRON LETTERS, 2009, 50 (05) : 552 - 554
  • [47] Diamines having a C2 symmetry.: Synthesis and application as ligands in the hydrogenation of prochiral substrates over rhodium complexes
    Shainyan, BA
    Ustinov, MV
    Bel'skii, VK
    Nindakova, LO
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2002, 38 (01) : 104 - 110
  • [48] Selective derivatization of resorcarenes.: 3.: C2-symmetrical and transcavity bridged bis-benzoxazines derived from C2ν-symmetrical tetratosylates
    Shivanyuk, A
    Schmidt, C
    Böhmer, V
    Paulus, EF
    Lukin, O
    Vogt, W
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (18) : 4319 - 4326
  • [49] Diamines Having a C2 Symmetry. Synthesis and Application as Ligands in the Hydrogenation of Prochiral Substrates over Rhodium Complexes
    B. A. Shainyan
    M. V. Ustinov
    V. K. Bel'skii
    L. O. Nindakova
    Russian Journal of Organic Chemistry, 2002, 38 : 104 - 110
  • [50] Synthesis and structural characterization of dizincocenes Zn2(η5-C5Me5)2 and Zn2(η5-C5Me4Et)2
    Grirrane, Abdessamad
    Resa, Irene
    Rodriguez, Arnor
    Carmona, Ernesto
    COORDINATION CHEMISTRY REVIEWS, 2008, 252 (15-17) : 1532 - 1539