Suppressing interlayer-gliding and Jahn-Teller effect in P2-type layered manganese oxide cathode via Mo doping for sodium-ion batteries

被引：56
作者：
Zhang, Lin [1 ,2 ]
Wang, Chenchen [2 ]
Liu, Yanchen [2 ]
Ren, Meng [2 ]
Du, Juan [1 ]
Chen, Aibing [1 ]
Li, Fujun [2 ]
机构：
[1] Hebei Univ Sci & Technol, Coll Chem & Pharmaceut Engn, Shijiazhuang 050018, Peoples R China
[2] Nankai Univ, Coll Chem, Renewable Energy Convers & Storage Ctr RECAST, Key Lab Adv Energy Mat Chem Minist Educ, Tianjin 300071, Peoples R China
来源：
CHEMICAL ENGINEERING JOURNAL | 2021年 / 426卷 / 426期
基金：
中国国家自然科学基金;
关键词：
Layered manganese-based oxides; Mo doping; Phase transition; High cycling capability; Sodium-ion batteries; PERFORMANCE;
D O I：
10.1016/j.cej.2021.130813
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Manganese-based layered oxides are one of the most promising cathode materials for sodium-ion batteries (SIBs) due to their high specific capacity and low cost of manganese and sodium. However, they are limited by the poor cycling stability caused by irreversible phase transitions and Jahn-Teller effect of Mn3+. Herein, Mo-doped P2Na(0.67)Mn(1-x)Mo(x)O(2) suppress the irreversible phase transition of P2-OP4 resulted from gliding of MnO2-slabs. It reveals that no phase transition occurs under high voltage via Mo elements doping into MnO6-layers. P2Na0.67Mn1-xMoxO2 displays high cyclic stability with a high capacity retention of 86.4% after 100 cycles and improved rate performance with an average working voltage of 2.61 V. The research provides a new perspective for designing novel layered oxide cathodes design toward high-performance SIBs.
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页数：7
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  • [1] Synthesis and characterization of high-temperature hexagonal P2-Na0.6MnO2 and its electrochemical behaviour as cathode in sodium cells
    Caballero, A
    Hernán, L
    Morales, J
    Sánchez, L
    Peña, JS
    Aranda, MAG
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (04) : 1142 - 1147
  • [2] Study of the Transition Metal Ordering in Layered NaxNix/2Mn1-x/2O2 (2/3 ≤ x ≤ 1) and Consequences of Na/Li Exchange
    Cabana, Jordi
    Chernova, Natasha A.
    Xiao, Jie
    Roppolo, Megan
    Aldi, Kellie A.
    Whittingham, M. Stanley
    Grey, Clare P.
    [J]. INORGANIC CHEMISTRY, 2013, 52 (15) : 8540 - 8550
  • [3] Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance
    Chao, Dongliang
    Zhu, Changrong
    Yang, Peihua
    Xia, Xinhui
    Liu, Jilei
    Wang, Jin
    Fan, Xiaofeng
    Savilov, Serguei V.
    Lin, Jianyi
    Fan, Hong Jin
    Shen, Ze Xiang
    [J]. NATURE COMMUNICATIONS, 2016, 7
  • [4] Cu2+ Dual-Doped Layer-Tunnel Hybrid Na0.6Mn1-xCuxO2 as a Cathode of Sodium-Ion Battery with Enhanced Structure Stability, Electrochemical Property, and Air Stability
    Chen, Ting-Ru
    Sheng, Tian
    Wu, Zhen-Guo
    Li, Jun-Tao
    Wang, En-Hui
    Wu, Chun-Jin
    Li, Hong-Tai
    Guo, Xiao-Dong
    Zhong, Ben-He
    Huang, Ling
    Sung, Shi-Gang
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (12) : 10147 - 10156
  • [5] High-performance rechargeable aqueous Zn-ion batteries with a poly(benzoquinonyl sulfide) cathode
    Dawut, Gulbahar
    Lu, Yong
    Miao, Licheng
    Chen, Jun
    [J]. INORGANIC CHEMISTRY FRONTIERS, 2018, 5 (06): : 1391 - 1396
  • [6] Intermediate honeycomb ordering to trigger oxygen redox chemistry in layered battery electrode
    de Boisse, Benoit Mortemard
    Liu, Guandong
    Ma, Jiangtao
    Nishimura, Shin-ichi
    Chung, Sai-Cheong
    Kiuchi, Hisao
    Harada, Yoshihisa
    Kikkawa, Jun
    Kobayashi, Yoshio
    Okubo, Masashi
    Yamada, Atsuo
    [J]. NATURE COMMUNICATIONS, 2016, 7
  • [7] Improving Energy Density and Structural Stability of Manganese Oxide Cathodes for Na-Ion Batteries by Structural Lithium Substitution
    de la Llave, Ezequiel
    Talaie, Elahe
    Levi, Elena
    Nayak, Prasant Kumar
    Dixit, Mudit
    Rao, Penki Tirupathi
    Hartmann, Pascal
    Chesneau, Hartmann Frederick
    Major, Dan Thomas
    Greenstein, Miri
    Aurbach, Doron
    Nazar, Linda F.
    [J]. CHEMISTRY OF MATERIALS, 2016, 28 (24) : 9064 - 9076
  • [8] STRUCTURAL CLASSIFICATION AND PROPERTIES OF THE LAYERED OXIDES
    DELMAS, C
    FOUASSIER, C
    HAGENMULLER, P
    [J]. PHYSICA B & C, 1980, 99 (1-4): : 81 - 85
  • [9] Layer Structured Materials for Advanced Energy Storage and Conversion
    Guo, Yanpeng
    Wei, Yaqing
    Li, Huiqiao
    Zhai, Tianyou
    [J]. SMALL, 2017, 13 (45)
  • [10] A New P2-Type Layered Oxide Cathode with Extremely High Energy Density for Sodium-Ion Batteries
    Hwang, Jang-Yeon
    Kim, Jongsoon
    Yu, Tae-Yeon
    Sun, Yang-Kook
    [J]. ADVANCED ENERGY MATERIALS, 2019, 9 (15)
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