Poly[3-methyl-1,3-oxazolidin-2-iminium[μ3-cyanido-tri-μ2-cyanido-κ9C:N-tricuprate(I)]]

被引：0
作者：
Rachid, Leena N. [1 ]
Corfield, Peter W. R. [1 ]
机构：
[1] Fordham Univ, Chem Dept, 441 East Fordham Rd, New York, NY 10458 USA
来源：
MOLBANK | 2021年 / 2021卷 / 03期
关键词：
oxazole; iminium; unexpected product; copper cyanide; network; cuprophilic; CHEMISTRY;
D O I：
10.3390/M1259
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The unexpected formation of an oxazole ring has occurred during synthesis of a copper(I) cyanide network polymer as part of our ongoing studies of the structural chemistry of these networks. Crystals of the title compound were formed during the synthesis of a previously reported CuCN network solid containing protonated N-methylethanolamine and have been characterized by single crystal X-ray structure analysis. The structure shows well-defined oxazole-2-iminium cations sitting in continuous channels along the short a-axis of the crystal in a new three-dimensional copper(I) cyanide polymeric network. Evidently, a reaction has occurred between the cyanide ion and the protonated N-methylethanolamine base.
引用
收藏
页数：7
相关论文
共 15 条
  • [1] Poly[1,3-Dimethyltetrahydropyrimidin-2(1H)-iminium [tri-μ2-cyanido-κ6C:N-dicuprate(I)]]
    Corfield, Peter W. R.
    Dayrit, Joseph R.
    [J]. MOLBANK, 2020, 2020 (04) : 1 - 6
  • [2] CORFIELD PWR, 2020, IUCRDATA, V0005
  • [3] Reactivity of chlorodeoxypseudoephedrines with oxo-, thio-, and selenocyanates
    Cruz, Alejandro
    Padilla-Martinez, Itzia Irene
    Garcia-Baez, Efren V.
    Contreras, Rosalinda
    [J]. TETRAHEDRON-ASYMMETRY, 2007, 18 (01) : 123 - 130
  • [4] The Cambridge Structural Database
    Groom, Colin R.
    Bruno, Ian J.
    Lightfoot, Matthew P.
    Ward, Suzanna C.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2016, 72 : 171 - 179
  • [5] A comprehensive review on biological activities of oxazole derivatives
    Kakkar, Saloni
    Narasimhan, Balasubramanian
    [J]. BMC CHEMISTRY, 2019, 13 (1)
  • [6] Synthesis, decomposition studies and crystal structure of a three-dimensional CuCN network structure with protonated N-methylethanolamine as the guest cation
    Koenigsmann, Christopher
    Rachid, Leena N.
    Sheedy, Christina M.
    Corfield, Peter W. R.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2020, 76 : 405 - +
  • [7] Lakham R., 1974, ADV HETEROCYCL CHEM, V17, P99, DOI DOI 10.1016/S0065-2725(08)60908-3
  • [8] MISIASZEK C, 1988, CR ACAD SCI II, V307, P1189
  • [9] Synthesis of Oxazole Analogs of Streptolidine Lactam
    Rynearson, Kevin D.
    Dutta, Sanjay
    Tran, Kiet
    Dibrov, Sergey M.
    Hermann, Thomas
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 2013 (32) : 7337 - 7342
  • [10] Cuprophilic Interactions in and between Molecular Entities
    Satyachand Harisomayajula, N., V
    Makovetskyi, Serhii
    Tsai, Yi-Chou
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (38) : 8936 - 8954
12