Studies of Physicochemical and Thermodynamic Properties of the Paramagnetic 1-Alkyl-3-methylimidazolium Ionic Liquids (EMIm)2[Co(NCS)4] and (BMIm)2[Co(NCS)4]

被引：12
|
作者：
Geppert-Rybczynska, Monika [1 ,3 ]
Lehmann, Jochen K. [1 ]
Peppel, Tim [2 ]
Koeckerling, Martin [2 ]
Heintz, Andreas [1 ]
机构：
[1] Univ Rostock, Inst Chem, Dept Phys Chem, D-18059 Rostock, Germany
[2] Univ Rostock, Inst Chem, Dept Inorgan Chem, D-18059 Rostock, Germany
[3] Univ Silesia, Inst Chem, Dept Phys Chem, PL-40006 Katowice, Poland
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2010年 / 55卷 / 12期
关键词：
SURFACE-TENSION MEASUREMENTS; AQUEOUS-SOLUTIONS; TEMPERATURE; VISCOSITY; DENSITY; TRANSPORT; FLUIDS; CATION; SALTS; LAW;
D O I：
10.1021/je100563b
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
This paper describes selected thermophysical properties of the newly obtained paramagnetic inky, opaque ionic liquid, 1-butyl-3-methylimidazolium tetraisothiocyanato-cobaltate(II) ((BMIm)(2)[Co(NCS)(4)]). Some properties of the homologous ionic liquid (IL), 1-ethy1-3-methylimidazolium tetraisothiocyanato-cobaltate(II) ((EMIm)(2)[Co(NCS)(4)]), have been presented earlier and are discussed here together with those for (BMIm)(2)[(Co(NCS)(4)]. On the basis of experimental densities, kinematic viscosities, conductivities, and surface tensions, some additional parameters have been determined, i.e., expansivity coefficients and surface thermodynamic properties. The influence of structural variation in the 1-alkyl-3-methylimidazolium cation is also discussed.
引用
收藏
页码：5534 / 5538
页数：5
相关论文
共 50 条
  • [1] Low-Viscosity Paramagnetic Ionic Liquids with Doubly Charged [Co(NCS)4]2- Ions
    Peppel, Tim
    Koeckerling, Martin
    Geppert-Rybczynska, Monika
    Ralys, Ricardas V.
    Lehmann, Jochen K.
    Verevkin, Sergey P.
    Heintz, Andreas
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (39) : 7116 - 7119
  • [2] Thermodynamic Properties of a Series of Closely Related Ionic Liquids Based on 1-Alkyl-3-methylimidazolium Hydrosulfate
    Xu Zhi-Ce
    Wang Jian-Ying
    Wang Xiao-Ling
    Hu Yong-Qi
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2011, 32 (08): : 1860 - 1864
  • [3] Prediction of the thermodynamic properties of 1-alkyl-3-methylimidazolium lactate ionic liquids [Cnmim][Lact] (n = 2, 3, 4, 5, and 6) by parachor
    Fang DaWei
    Tong Jing
    Guan Wei
    Wang Han
    Yang JiaZhen
    SCIENCE CHINA-CHEMISTRY, 2010, 53 (12) : 2564 - 2570
  • [4] 1-Alkyl-3-methylimidazolium alkanesulfonate ionic liquids, [CnH2n+1mim][CkH2k+1SO3]: synthesis and physicochemical properties
    Blesic, Marijana
    Swadzba-Kwasny, Malgorzata
    Belhocine, Tayeb
    Gunaratne, H. Q. Nimal
    Canongia Lopes, Jose N.
    Gomes, Margarida F. Costa
    Padua, Agilio A. H.
    Seddon, Kenneth R.
    Rebelo, Luis Paulo N.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (39) : 8939 - 8948
  • [5] Enhanced CO2 Capture in Binary Mixtures of 1-Alkyl-3-methylimidazolium Tricyanomethanide Ionic Liquids with Water
    Romanos, George E.
    Zubeir, Lawien F.
    Likodimos, Vlassis
    Falaras, Polycarpos
    Kroon, Maaike C.
    Iiev, Boyan
    Adamova, Gabriela
    Schubert, Thomas J. S.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2013, 117 (40) : 12234 - 12251
  • [6] Prediction of the thermodynamic properties of 1-alkyl-3-methylimidazolium lactate ionic liquids [Cnmim][Lact] (n = 2, 3, 4, 5, and 6) by parachor
    DaWei Fang
    Jing Tong
    Wei Guan
    Han Wang
    JiaZhen Yang
    Science China Chemistry, 2010, 53 : 2564 - 2570
  • [7] Saturation Properties of 1-Alkyl-3-methylimidazolium Based Ionic Liquids
    Rane, Kaustubh S.
    Errington, Jeffrey R.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2014, 118 (29) : 8734 - 8743
  • [8] Prediction of the thermodynamic properties of 1-alkyl-3-methylimidazolium lactate ionic liquids [Cnmim][Lact]（n=2,3,4,5,and 6） by parachor
    FANG DaWei 1
    Science China(Chemistry), 2010, (12) : 2564 - 2570
  • [9] Thermodynamic and transport properties of ionic liquids, 1-alkyl-3-methylimidazolium thiocyanate in the aqueous lithium halides solutions
    Shekaari, Hemayat
    Zafarani-Moattar, Mohammed Taghi
    Golmohammadi, Behrang
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2020, 141
  • [10] Viscosity of ionic liquid mixtures of 1-alkyl-3-methylimidazolium hexafluorophosphate + CO2
    Tomida, Daisuke
    Kenmochi, Satoshi
    Qiao, Kun
    Bao, Quanxi
    Yokoyama, Chiaki
    FLUID PHASE EQUILIBRIA, 2011, 307 (02) : 185 - 189
12345