Catalytic epoxidation by perrhenate through the formation of organic-phase supramolecular ion pairs

被引：18

作者：

Cokoja, Mirza ^{[1
,2
]}

Markovits, Iulius I. E. ^{[1
,2
]}

Anthofer, Michael H. ^{[1
,2
]}

Poplata, Saner ^{[1
,2
]}

Poethig, Alexander ^{[1
,2
]}

Morris, Danny S. ^{[3
]}

Tasker, Peter A. ^{[3
]}

Herrmann, Wolfgang A. ^{[1
,2
]}

Kuehn, Fritz E. ^{[1
,2
]}

Love, Jason B. ^{[3
]}

机构：

[1] Tech Univ Munich, Catalysis Res Ctr, D-85747 Garching, Germany

[2] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany

[3] Univ Edinburgh, EaStCHEM Sch Chem, Edinburgh EH9 3FJ, Midlothian, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 16期

基金：

英国工程与自然科学研究理事会;

关键词：

HYDROGEN-PEROXIDE; COORDINATION CHEMISTRY; ACTIVATION; OXIDATION; LIGANDS; COMPLEX; ALKENES;

D O I：

10.1039/c4cc10235e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Organic-phase supramolecular ion pair (SIP) host-guest assemblies of perrhenate anions (ReO4-) with ammonium amide receptor cations are reported. These compounds act as catalysts for the epoxidation of alkenes by aqueous hydrogen peroxide under biphasic conditions and can be recycled several times with no loss in activity.

引用

页码：3399 / 3402

页数：4

共 33 条

[1] Fluorinated Solvents in Methyltrioxorhenium-Catalyzed Olefin Epoxidations [J].

Altmann, Philipp ;

Cokoja, Mirza ;

Kuehn, Fritz E. .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (19) :3235-3239

[2] H-Donor Anion Acceptor Organocatalysis-The Ionic Electrophile Activation Approach [J].

Beckendorf, Stephan ;

Asmus, Soeren ;

Mancheno, Olga Garcia .

CHEMCATCHEM, 2012, 4 (07) :926-936

[3] Olefin Epoxidation with a New Class of Ansa-Molybdenum Catalysts in Ionic Liquids [J].

Betz, Daniel ;

Raith, Alexander ;

Cokoja, Mirza ;

Kuehn, Fritz E. .

CHEMSUSCHEM, 2010, 3 (05) :559-562

[4] Highly efficient catalysts in directed oxygen-transfer processes:: Synthesis, structures of novel manganese-containing heteropolyanions, and applications in regioselective epoxidation of dienes with hydrogen peroxide [J].

Bösing, M ;

Nöh, A ;

Loose, I ;

Krebs, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (29) :7252-7259

[5] Asymmetric Ion-Pairing Catalysis [J].

Brak, Katrien ;

Jacobsen, Eric N. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (02) :534-561

[6] CONVERSION OF CHOLESTANOL TO 12-KETOCHOLESTANOL AND TO DELTA14-CHOLESTENOL AND DELTA8(14)-CHOLESTENOL BY REMOTE OXIDATION [J].

BRESLOW, R ;

BALDWIN, SW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (03) :732-&

[7] Recent advances in cooperative ion pairing in asymmetric organocatalysis [J].

Briere, Jean-Francois ;

Oudeyer, Sylvain ;

Dalla, Vincent ;

Levacher, Vincent .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (05) :1696-1707

[8] Recent advances in catalytic asymmetric epoxidation using the environmentally benign oxidant hydrogen peroxide and its derivatives [J].

De Faveri, Giorgio ;

Ilyashenko, Gennadiy ;

Watkinson, Michael .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (03) :1722-1760

[9] ADVANCES IN PHASE-TRANSFER CATALYSIS [J].

DEHMLOW, EV .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (08) :493-505

[10] Design and Function of Pre-organised Outer-Sphere Amidopyridyl Extractants for Zinc(II) and Cobalt(II) Chlorometallates: The Role of C-H Hydrogen Bonds [J].

Ellis, Ross J. ;

Chartres, Jy ;

Henderson, David K. ;

Cabot, Rafel ;

Richardson, Patricia R. ;

White, Fraser J. ;

Schroeder, Martin ;

Turkington, Jennifer R. ;

Tasker, Peter A. ;

Sole, Kathryn C. .

CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (25) :7715-7728

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