New oligomeric hyper-branched esters incorporating tetrathiafulvalene: Synthesis, electrochemistry and charge-transfer complexes

被引：12

作者：

Bryce, MR

Devonport, W

机构：

[1] Department of Chemistry, University of Durham

来源：

SYNTHETIC METALS | 1996年 / 76卷 / 1-3期

关键词：

esters; tetrathiafulvalene; synthesis; electrochemistry;

D O I：

10.1016/0379-6779(95)03477-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The synthesis of new hyper-branched esters substituted with peripheral tetrathiafulvalene (TIF) groups is described. The use of a 4,4'-diphenylether core provides compounds 12-14 which ate shelf-stable and possess good solubility in organic solvents. The oligomeric TTF systems display reversible redox behaviour and semiconducting charge-transfer complexes are formed with tetracyano-p-quinodimethane (TCNQ).

引用

页码：305 / 307

页数：3

共 18 条

[1] OLIGOMERIC TETRATHIAFULVALENES - EXTENDED DONORS FOR INCREASING THE DIMENSIONALITY OF ELECTRICAL-CONDUCTION [J].