How to predict the physical properties of ionic liquids: A volume-based approach

被引：263

作者：

Slattery, John M.

Daguenet, Corinne

Dyson, Paul J.

Schubert, Thomas J. S.

Krossing, Ingo

机构：

[1] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany

[2] Ecole Polytech Fed Lausanne, Inst Sci & Engn Chim, CH-1015 Lausanne, Switzerland

[3] IoLiTec, D-79211 Denzlingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 28期

关键词：

ionic liquids; molecular volumes; physical properties; predictive methods; sustainable chemistry;

D O I：

10.1002/anie.200700941

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The molecular volume Vm (that is, the sum of the ionic volumes Vion of the constituent ions) of an ionic liquid (IL) in combination with an anion-dependent empirical relationship is all one needs to predict physical properties such as viscosity, conductivity, and density of [N(CN)2]-, [BF4]-, [PF6]-, and [N(SO2CF3) 2]- ionic liquids, including those which may as yet only exist on paper. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5384 / 5388

页数：5

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