Controlled synthesis of polymer brushes by "Living" free radical polymerization techniques

被引：861
作者：
Husseman, M
Malmström, EE
McNamara, M
Mate, M
Mecerreyes, D
Benoit, DG
Hedrick, JL
Mansky, P
Huang, E
Russell, TP
Hawker, CJ
机构：
[1] IBM Corp, Almaden Res Ctr, Ctr Polymer Interfaces & Macromol Assemblies, San Jose, CA 95120 USA
[2] Univ Massachusetts, Polymer Sci & Engn Dept, Silvio O Conte Natl Ctr Polymer Res, Amherst, MA 01003 USA
来源：
MACROMOLECULES | 1999年 / 32卷 / 05期
关键词：
D O I：
10.1021/ma981290v
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The preparation of a wide variety of unique polymer brush structures can be accomplished by "living" free radical polymerization of vinyl monomers from surface-tethered alkoxyamines or from tethered alpha-halo esters in the presence of (PPh3)(2)NiBr2. The use of a "living" free radical process permits the molecular weight and polydispersity of the covalently attached polymer chains to be accurately controlled while also allowing the formation of block copolymers by the sequential growth of monomers from the surface. These block and random copolymer brushes have been used to control surface properties.
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页码：1424 / 1431
页数：8
相关论文
共 42 条
[1]   Influence of anchor block size on the thickness of adsorbed block copolymer layers [J].
Belder, GF ;
tenBrinke, G ;
Hadziioannou, G .
LANGMUIR, 1997, 13 (15) :4102-4105
[2]   ORGANIZATION OF THE LAYERS OF POLYETHYLENE OXIDE GRAFTED WITH DIFFERENT DENSITIES ON SILICA [J].
BENOUADA, H ;
HOMMEL, H ;
LEGRAND, AP ;
BALARD, H ;
PAPIRER, E .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1988, 122 (02) :441-449
[3]   THE TERMINAL GRAFTING OF POLY(ETHYLENE OXIDE) CHAINS TO SILICA SURFACES [J].
BRIDGER, K ;
VINCENT, B .
EUROPEAN POLYMER JOURNAL, 1980, 16 (10) :1017-1021
[4]   LIVING RADICAL POLYMERIZATION - KINETIC RESULTS [J].
CATALA, JM ;
BUBEL, F ;
HAMMOUCH, SO .
MACROMOLECULES, 1995, 28 (24) :8441-8443
[5]   Grafting of poly(gamma-benzyl-L-glutamate) on chemically modified silicon oxide surfaces [J].
Chang, YC ;
Frank, CW .
LANGMUIR, 1996, 12 (24) :5824-5829
[6]   SELF-ASSEMBLY OF BLOCK-COPOLYMERS WITH A STRONGLY CHARGED AND A HYDROPHOBIC BLOCK IN A SELECTIVE, POLAR-SOLVENT - MICELLES AND ADSORBED LAYERS [J].
DAN, N ;
TIRRELL, M .
MACROMOLECULES, 1993, 26 (16) :4310-4315
[7]  
Dao J, 1998, J POLYM SCI POL CHEM, V36, P2161, DOI 10.1002/(SICI)1099-0518(19980915)36:12<2161::AID-POLA24>3.0.CO
[8]  
2-3
[9]   Controlled graft polymerization of methyl methacrylate on silicon substrate by the combined use of the Langmuir-Blodgett and atom transfer radical polymerization techniques [J].
Ejaz, M ;
Yamamoto, S ;
Ohno, K ;
Tsujii, Y ;
Fukuda, T .
MACROMOLECULES, 1998, 31 (17) :5934-5936
[10]   Controlled radical polymerization of methacrylic monomers in the presence of a bis(ortho-chelated) arylnickel(II) complex and different activated alkyl halides [J].
Granel, C ;
Dubois, P ;
Jerome, R ;
Teyssie, P .
MACROMOLECULES, 1996, 29 (27) :8576-8582
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