Effect of bathocuproine buffer layer in small molecule organic solar cells with inverted structure

被引:6
作者
Hao, Xia [1 ]
Wang, Shenghao [1 ]
Sakurai, Takeaki [1 ,2 ]
Akimoto, Katsuhiro [1 ]
机构
[1] Univ Tsukuba, Inst Appl Phys, Tsukuba, Ibaraki 3058573, Japan
[2] Japan Sci & Technol Agcy JST, PRESTO, Kawaguchi, Saitama 3320012, Japan
关键词
DEGRADATION; DEPOSITION; FILMS;
D O I
10.7567/JJAP.54.04DK06
中图分类号
O59 [应用物理学];
学科分类号
摘要
Inverted organic solar cells (OSCs) based on boron subphthalocynine chloride (SubPc) and fullerene (C-60) were fabricated and the device structure was optimized by inserting a bathocuproine (C26H20N2) buffer layer. The power conversion efficiency was greatly improved from 0.8 to 1.6%. The roles of bathocuproine in this inverted device were investigated by photoluminescence and transient photovoltage/photocurrent measurements. The results show that the bathocuproine in the device not only blocks the exciton quenching, but also prohibits the build-up of charge trapping and suppresses the trap-assisted recombination. (C) 2015 The Japan Society of Applied Physics
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页数:5
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共 30 条
[1]   Relationship between energetic disorder and open-circuit voltage in bulk heterojunction organic solar cells [J].
Blakesley, James C. ;
Neher, Dieter .
PHYSICAL REVIEW B, 2011, 84 (07)
[2]   Effect of LiF/metal electrodes on the performance of plastic solar cells [J].
Brabec, CJ ;
Shaheen, SE ;
Winder, C ;
Sariciftci, NS ;
Denk, P .
APPLIED PHYSICS LETTERS, 2002, 80 (07) :1288-1290
[3]   COMMENTS ON CLASSICAL THEORY OF ENERGY-TRANSFER [J].
CHANCE, RR ;
PROCK, A ;
SILBEY, R .
JOURNAL OF CHEMICAL PHYSICS, 1975, 62 (06) :2245-2253
[4]   Recombination in polymer-fullerene bulk heterojunction solar cells [J].
Cowan, Sarah R. ;
Roy, Anshuman ;
Heeger, Alan J. .
PHYSICAL REVIEW B, 2010, 82 (24)
[5]   In situ characterization of the oxidative degradation of a polymeric light emitting device [J].
Cumpston, B.H. ;
Parker, I.D. ;
Jensen, K.F. .
1997, American Inst of Physics, Woodbury, NY, United States (81)
[6]   Ultrathin organic films grown by organic molecular beam deposition and related techniques [J].
Forrest, SR .
CHEMICAL REVIEWS, 1997, 97 (06) :1793-1896
[7]   Electro-optical study of subphthalocyanine in a bilayer organic solar cell [J].
Gommans, Hans ;
Cheyns, David ;
Aernouts, Tom ;
Girotto, Claudio ;
Poortmans, Jef ;
Heremans, Paul .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (15) :2653-2658
[8]   Barium: An Efficient Cathode Layer for Bulk-heterojunction Solar Cells [J].
Gupta, Vinay ;
Kyaw, Aung Ko Ko ;
Wang, Dong Hwan ;
Chand, Suresh ;
Bazan, Guillermo C. ;
Heeger, Alan J. .
SCIENTIFIC REPORTS, 2013, 3
[9]   Novel cathode buffer layer of Ag-doped bathocuproine for small molecule organic solar cell with inverted structure [J].
Hao, Xia ;
Wang, Shenghao ;
Fu, Wei ;
Sakurai, Takeaki ;
Masuda, Shigeru ;
Akimoto, Katsuhiro .
ORGANIC ELECTRONICS, 2014, 15 (08) :1773-1779
[10]   Water and oxygen induced degradation of small molecule organic solar cells [J].
Hermenau, Martin ;
Riede, Moritz ;
Leo, Karl ;
Gevorgyan, Suren A. ;
Krebs, Frederik C. ;
Norrman, Kion .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2011, 95 (05) :1268-1277