The synthesis of homochiral hybrid diamines derived from 1,1′-binaphthyl-2,2′-diamine and α-amino acids

被引：8

作者：

Kowalczyk, B

Tarnowska, A

Weselinski, L

Jurczak, J

机构：

[1] Warsaw Univ, Dept Organ Chem, PL-02093 Warsaw, Poland

[2] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland

来源：

SYNLETT | 2005年 / 15期

关键词：

synthesis; binaphthyl moiety; homochiral diamines; diastereomers; axial chirality; amino acids;

D O I：

10.1055/s-2005-872260

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient procedure for the preparation of homochiral diamines is presented. Coupling of racemic 1,1'-binaphthyl-2,2'-diamine with natural N-protected amino acids afforded the corresponding diastereomeric precursors which, following chromatographic separation and deprotection, gave the desired products in good yields. These compounds, called herein hybrid compounds, possess two different stereogenic elements, i.e., the centre containing the L-amino acid residues and the C-2 axis, resulting from the 1,1'-binaphthyl moiety.

引用

页码：2373 / 2375

页数：3

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