N,N,N′,N′-tetrakis(diphenylphosphanyl)-1,3-diaminobenzene as a bis-chelate ligand in [1,3-{cis-Mo(CO)4(PPh2)2N}2C6H4]

被引：30

作者：

Majoumo, F ^{[1
]}

Lönnecke, P ^{[1
]}

Kühl, O ^{[1
]}

Hey-Hawkins, E ^{[1
]}

机构：

[1] Univ Leipzig, Inst Anorgan Chem, Leipzig, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 02期

关键词：

molybdenum; aminophosphine ligands; dinuclear complexes; molecular structures;

D O I：

10.1002/zaac.200300324

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,3-Diaminobenzene reacts readily with PPh2Cl to give N,N,N',N'-tetrakis(diphenylphosphanyl)-1,3-diaminobenzene (1) in excellent yield. The dinuclear complex [1,3-{cis-Mo(CO)(4)(PPh2)(2)N}(2)C6H4] (2) is obtained in high yield from I and cis-[Mo(CO)(4)(NCEt)(2)]. Compounds 1 and 2 were characterized by NMR spectroscopy (H-1, C-13, P-31) and by crystal structure determination. The latter shows the formation of a bis-chelate complex with Mo-P-N-P four-membered rings.

引用

页码：305 / 308

页数：4