Nature of weak inter- and intramolecular interactions in crystals 3. Intermolecular P=O...C=O contact in crystals of phenyl methylisopropoxyphosphorylformate

被引：1

作者：

Lyssenko, KA ^{[1
]}

Odinets, IL ^{[1
]}

Kazakov, PV ^{[1
]}

Pasechnik, MP ^{[1
]}

Antipin, MY ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2005年 / 54卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

phosphorylformic acid derivatives; P=O...C=O contacts; nature of P-O chemical bonding; electron density distribution; topological theory of Atoms in Molecules; X-ray diffraction data;

D O I：

10.1007/s11172-005-0290-8

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phenyl methylisopropoxyphosphorylformate was studied by high-resolution X-ray diffraction. The chemical bonding in the vicinity of the phosphoryl group was studied by analyzing the deformation electron density, the Laplacian of the electron density, and the electron localization function. A P=O center dot center dot center dot C=O intermolecular contact was revealed and its nature was analyzed.

引用

页码：560 / 565

页数：6

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