The synthesis of densely grafted copolymers by atom transfer radical polymerization

被引：529

作者：

Beers, KL

Gaynor, SG

Matyjaszewski, K

Sheiko, SS

Möller, M

机构：

[1] Carnegie Mellon Univ, Dept Chem, Mellon Inst, Pittsburgh, PA 15213 USA

[2] Univ Ulm, D-89069 Ulm, Germany

来源：

MACROMOLECULES | 1998年 / 31卷 / 26期

关键词：

D O I：

10.1021/ma981402i

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Densely grafted brush copolymers was synthesized by atom transfer radical polymerization to obtain well-defined molecules which can be imaged and whose dimensions can be visualized by atomic force microscopy. The side reactions were minimized and the reaction conditions were optimized to obtain well-defined polymers. These conditions include temperature, and varying concentration of all reagents: macroinitiator, monomer, catalyst (CuIBr) and deactivator (CuIIBr2).

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页码：9413 / 9415

页数：3

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