Catalytic asymmetric carbon-carbon bond-forming reactions in aqueous media

被引：69

作者：

Bhowmick, Sudipto ^{[1
]}

Bhowmick, Kartick C. ^{[1
]}

机构：

[1] Visva Bharati Univ, Dept Chem, Div Organ Synth, Bolpur 731235, W Bengal, India

来源：

TETRAHEDRON-ASYMMETRY | 2011年 / 22卷 / 23期

关键词：

DIRECT ALDOL REACTION; ENANTIOSELECTIVE MICHAEL ADDITION; DIELS-ALDER REACTIONS; WATER-COMPATIBLE ORGANOCATALYSTS; MANNICH-TYPE REACTIONS; SMALL ORGANIC-MOLECULE; GALLIUM LEWIS-ACID; ARYLBORONIC ACIDS; HIGHLY EFFICIENT; ALPHA; BETA-UNSATURATED ALDEHYDES;

D O I：

10.1016/j.tetasy.2011.11.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The development of enantioselective transformations has been the subject of numerous research efforts. In recent years, a variety of efficient asymmetric catalysts for different organic reactions in aqueous media have been introduced. This review summarizes an analysis of chiral metal complex reactions catalyzed as well as organocatalyzed reactions in aqueous media. The applications of a variety of chiral ligands alone, or in association with metal complexes, in water alone, as well as other conditions such as reactions in water in the presence of surfactants or in mixtures of water and organic solvents are described. Complete up to date results concerning asymmetric aldol reactions, 1,4-conjugate addition reactions, Mannich reactions, Diels-Alder reactions, Friedel-Craft reactions and so on have appeared in the literature. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：1945 / 1979

页数：35

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