Use of Optical Spectroscopy Methods to Determine the Solubility Limit for Nitrogen in Diamond Single Crystals Synthesized by Chemical Vapor Deposition

被引：13

作者：

Khomich, A. A. ^{[1
,2
]}

Kudryavtsev, O. S. ^{[1
]}

Bolshakov, A. P. ^{[1
,3
]}

Khomich, A. V. ^{[2
]}

Ashkinazi, E. E. ^{[1
,3
]}

Ralchenko, V. G. ^{[1
,3
]}

Vlasov, I. I. ^{[1
,3
]}

Konov, V. I. ^{[1
,3
]}

机构：

[1] Russian Acad Sci, AM Prokhorov Inst Gen Phys, Moscow 119991, Russia

[2] Russian Acad Sci, VA Kotelnikov Inst Radioengn & Elect, Fryazino, Moscow Oblast, Russia

[3] Natl Res Nucl Univ MEPhI, Moscow, Russia

来源：

JOURNAL OF APPLIED SPECTROSCOPY | 2015年 / 82卷 / 02期

基金：

俄罗斯科学基金会;

关键词：

luminescence; diamond; impurity center; synthesis by chemical vapor deposition; nitrogen-vacancy center; RATE HOMOEPITAXIAL GROWTH; MICROWAVE PLASMA CVD; CENTERS; NANODIAMONDS;

D O I：

10.1007/s10812-015-0092-1

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

We have studied the upper limits for incorporation of nitrogen and formation of arrays of nitrogen-vacancy (NV) color centers in optical-quality single-crystalline diamond synthesized by chemical vapor deposition (CVD). The CVD diamond samples were grown in a microwave plasma in methane-hydrogen mixtures with high content (200-2000 ppm) of the nitrogen dopant in the gas mixture, and were analyzed using Raman and photoluminescence spectroscopy. From the UV absorption spectra, we established that the solubility limit for substitutional nitrogen in the studied material is close to 2 center dot 10(18) cm(-3) (under typical synthesis conditions), which lets us in particular form arrays of NV center with similar concentrations by means of irradiation and annealing.

引用

页码：242 / 247

页数：6

共 25 条

[1] Coupled effect of nitrogen addition and surface temperature on the morphology and the kinetics of thick CVD diamond single crystals [J].

Achard, J. ;

Silva, F. ;

Brinza, O. ;

Tallaire, A. ;

Gicquel, A. .

[2] Diamonds with a high density of nitrogen-vacancy centers for magnetometry applications [J].

Acosta, V. M. ;

Bauch, E. ;

Ledbetter, M. P. ;

Santori, C. ;

Fu, K. -M. C. ;

Barclay, P. E. ;

Beausoleil, R. G. ;

Linget, H. ;

Roch, J. F. ;

Treussart, F. ;

Chemerisov, S. ;

Gawlik, W. ;

Budker, D. .

PHYSICAL REVIEW B, 2009, 80 (11)

[3]

Aharonovich I, 2011, NAT PHOTONICS, V5, P397, DOI [10.1038/NPHOTON.2011.54, 10.1038/nphoton.2011.54]

[4]

Balasubramanian G, 2009, NAT MATER, V8, P383, DOI [10.1038/nmat2420, 10.1038/NMAT2420]

[5] The effect of nitrogen addition during high-rate homoepitaxial growth of diamond by microwave plasma CVD [J].

Chayahara, A ;

Mokuno, Y ;

Horino, Y ;

Takasu, Y ;

Kato, H ;

Yoshikawa, H ;

Fujimori, N .

[6] Production of oriented nitrogen-vacancy color centers in synthetic diamond [J].

Edmonds, A. M. ;

D'Haenens-Johansson, U. F. S. ;

Cruddace, R. J. ;

Newton, M. E. ;

Fu, K. -M. C. ;

Santori, C. ;

Beausoleil, R. G. ;

Twitchen, D. J. ;

Markham, M. L. .

PHYSICAL REVIEW B, 2012, 86 (03)

[7] Beyond the Sparkle: The Impact of Nanodiamonds as Biolabeling and Therapeutic Agents [J].

Ho, Dean .

ACS NANO, 2009, 3 (12) :3825-3829

[8] Single defect centres in diamond: A review [J].

Jelezko, F. ;

Wrachtrup, J. .

PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2006, 203 (13) :3207-3225

[9]

Jelezko F, 2001, SINGLE MOL, V2, P255, DOI 10.1002/1438-5171(200112)2:4<255::AID-SIMO255>3.0.CO

[10]

2-D

← 1 2 3 →