Introducing a pyrazole/imidazole based hybrid cyclophane: a hydrogen bond sensor and binucleating ligand precursor

被引：33

作者：

Altmann, Philipp J.

Jandl, Christian

Poethig, Alexander ^{[1
]}

机构：

[1] Tech Univ Munich, Catalysis Res Ctr, D-85747 Garching, Germany

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 25期

关键词：

TETRACARBENE COMPLEXES; IMIDAZOLIUM;

D O I：

10.1039/c5dt01775k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel cyclophane consisting of methylene-bridged imidazolium- and pyrazole-moieties (calix[4]imidazolium[2]pyrazole) and two of its applications are presented. First, supramolecular recognition of an acetonitrile molecule by hydrogen bonding in the solid state is examined. Second, the capability to act as a ligand precursor is shown by the synthesis and characterisation of the respective dinuclear NHC-nickel(II) complex.

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收藏

页码：11278 / 11281

页数：4

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