High-yield generation of a long-lived charge-separated state in diphenylacetylene-modified DNA

被引：27
|
作者：
Takada, T [1 ]
Kawai, K [1 ]
Fujitsuka, M [1 ]
Majima, T [1 ]
机构：
[1] Osaka Univ, Inst Sci & Ind Res SANKEN, Osaka 5670047, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 01期
关键词：
charge transfer; DNA; electrochemistry; time-resolved spectroscopy;
D O I：
10.1002/anie.200502568
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Base jumping: A long-lived charge-separated state has been generated in high yield for DNA modified with a diphenylacetylene derivative (DPA) through an adenine (A)-base-hopping mechanism (see diagram). Modulation of the redox properties of the photosensitizer and bridge bases (e.g., by employing a brominated adenine (BrA)) can improve the yield of the charge-separated state. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：120 / 122
页数：3
相关论文
共 50 条
  • [1] Long-lived charge-separated state leading to DNA damage through hole transfer
    Kawai, K
    Takada, T
    Nagai, T
    Cai, XC
    Sugimoto, A
    Fujitsuka, M
    Majima, T
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (52) : 16198 - 16199
  • [2] Rational design of a phthalocyanine-perylenediimide dyad with a long-lived charge-separated state
    Blas-Ferrando, Vicente M.
    Ortiz, Javier
    Bouissane, Latifa
    Ohkubo, Kei
    Fukuzumi, Shunichi
    Fernandez-Lazaro, Fernando
    Sastre-Santos, Angela
    CHEMICAL COMMUNICATIONS, 2012, 48 (50) : 6241 - 6243
  • [3] Promoted Charge Separation and Long-Lived Charge-Separated State in Porphyrin-Viologen Dyad Nanoparticles
    Cai, Bin
    Song, Hongwei
    Brnovic, Andjela
    Pavliuk, Mariia V. V.
    Hammarstroem, Leif
    Tian, Haining
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (34) : 18687 - 18692
  • [4] An extremely long-lived charge-separated state of zinc tetraphenylporphyrin coordinated with pyridylnaphthalene-diimide
    Saito, Kenji
    Kashiwagi, Yukiyasu
    Ohkubo, Kei
    Fukuzumi, Shunichi
    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2006, 10 (12) : 1371 - 1379
  • [5] A small cationic donor-acceptor iridium complex with a long-lived charge-separated state
    Geiss, Barbara
    Lambert, Christoph
    CHEMICAL COMMUNICATIONS, 2009, (13) : 1670 - 1672
  • [6] Long-lived triplet charge-separated state in naphthalenediimide based donor-acceptor systems
    Aster, Alexander
    Rumble, Christopher
    Bornhof, Anna-Bea
    Huang, Hsin-Hua
    Sakai, Naomi
    Solomek, Tomas
    Matile, Stefan
    Vauthey, Eric
    CHEMICAL SCIENCE, 2021, 12 (13) : 4908 - 4915
  • [7] Long-Lived Charge-Separated States in Ligand-Stabilized Silver Clusters
    Pelton, Matthew
    Tang, Yun
    Bakr, Osman M.
    Stellacci, Francesco
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (29) : 11856 - 11859
  • [8] Sequential energy and electron transfer in an artificial reaction center: Formation of a long-lived charge-separated state
    Luo, C
    Guldi, DM
    Imahori, H
    Tamaki, K
    Sakata, K
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (28) : 6535 - 6551
  • [9] Naphthalenediimide/Iodobismuthate Hybrid Heterostructures: Water Resistance and Long-Lived Charge-Separated States
    Zhang, Shu-Quan
    Fang, Hua
    Chen, Fu-Hai
    Lin, Mei-Jin
    INORGANIC CHEMISTRY, 2023, 62 (48) : 19706 - 19719
  • [10] Laterally Bound Co Porphyrin on CdTe QD: A Long-Lived Charge-Separated Nanocomposite
    Dana, Jayanta
    Khan, Ramsha
    Weckman, Timo
    Honkala, Karoliina
    Tkachenko, Nikolai V.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2023, 127 (21): : 10164 - 10173
12345