Constant Potential and Constant Current Electrolysis: An Introduction and Comparison of Different Techniques for Organic Electrosynthesis

被引：56

作者：

Rafiee, Mohammad ^{[1
]}

Mayer, Mikayla N. ^{[1
]}

Punchihewa, Buwanila T. ^{[1
]}

Mumau, Matthew R. ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Kansas City, MO 64110 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 86卷 / 22期

关键词：

ELECTROCHEMICAL OXIDATION; DIPHENYL DISELENIDE; ALCOHOL OXIDATION; ANODIC-OXIDATION; REACTIVITY; ACIDS;

D O I：

10.1021/acs.joc.1c01391

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electrosynthesis involves transferring charge between two electrodes to promote chemical reactions by applying potential. The modes of controlling the current and potential can affect the reaction mechanism, product distribution and yields, and add a control factor for reaction optimization. In this Synopsis, theoretical discussion is applied to specific case studies from the literature to illustrate methods of adjusting and tracking electrical parameters for the optimization and monitoring of electroorganic reactions.

引用

页码：15866 / 15874

页数：9

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