In situ neutron diffraction study on Pd-doped Mg0.65SC0.35 electrode material

The behavior of a negative composite electrode made of Pd-doped Mg0.65SC0.35 active material has been studied dynamically by in situ neutron diffraction during a complete charge-discharge electrochemical cycle starting from a virgin alloy. From the analysis of the collected diffraction patterns, phase identification, phase amounts, structural changes and cell volume evolutions have been determined as a function of the electrochemical state of (dis)charge. For the first charge, the active material shows a structural transformation from body-centered cubic (bee) to face-centered cubic (fee). During the following discharge, a two-phase behavior with equilibrium between a hydrogen-poor fee phase and a hydrogen-rich one is observed. Complete discharge beyond the hydrogen-poor phase was not reached and a good electrochemical reversibility is expected between the hydrogen-poor and the hydrogen-rich fee phases for this electrode material. (C) 2008 Elsevier Inc. All rights reserved.