(1R, 2R, 3R, 4R, 5S)-2,3-bis[(2S′)-2-acetoxy-2-phenylacetoxy]-4-azido-1-[(2,4-dinitrophenyl) hydrazonomethyl] bicyclo[3.1.0]-hexane

被引:2
作者
Li, Jing [2 ]
Lowary, Todd L. [2 ]
McDonald, Robert [1 ]
机构
[1] Univ Alberta, Dept Chem, Xray Crystallog Lab, Edmonton, AB T6G 2G2, Canada
[2] Univ Alberta, Dept Chem, Alberta Ingenu Ctr Carbohydrate Sci, Edmonton, AB T6G 2G2, Canada
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S1600536808000718
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C38H29N7O12, the five-membered ring adopts an envelope conformation in which the flap is cis to the cyclo-propane group. This conformation is similar to those of other bicyclo-[3.1.0]hexane analogues for which crystal structures have been reported. The absolute configuration of the stereogenic centers on the cyclo-pentane ring, as determined by comparison with the known configurations of the stereogenic centers in the (2S)-2-acet-oxy-2- phenyl-acet-oxy groups, is 1(R), 2(R), 3(R), 4(R) and 5(S). An intramolecular N - H⋯O hydrogen bond is present.
引用
收藏
页码:O459 / U2487
页数:14
相关论文
共 16 条
  • [1] p-Tolyl 2,3-anhydro-5,6-O-isopropylidene-1-thio-β-D-gulofuranoside
    Bai, Y
    Lowary, TL
    Ferguson, MJ
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 : O2201 - O2203
  • [2] A [3.1.0]-fused 2',3'-modified beta-D-pyrazolo[3,4-d]pyrimidine nucleoside
    Biswas, G
    Chandra, T
    Garg, N
    Bhakuni, DS
    Pramanik, A
    Avasthi, K
    Maulik, PR
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 2563 - 2566
  • [3] *BRUK AXS INC, 2001, SMART VERS 5 054
  • [4] *BRUK AXS INC, 2003, SADABS VERS 2 10 SAI
  • [5] Synthesis and conformational investigation of methyl 4a-carba-D-arabinofuranosides
    Callam, CS
    Lowary, TL
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (26) : 8961 - 8972
  • [6] Sensitivity of 1JC1-H1 magnitudes to anomeric stereochemistry in 2,3-anhydro-O-furanosides
    Callam, CS
    Gadikota, RR
    Lowary, TL
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (13) : 4549 - 4558
  • [7] Total synthesis of both methyl 4a-carba-D-arabinofuranosides
    Callam, CS
    Lowary, TL
    [J]. ORGANIC LETTERS, 2000, 2 (02) : 167 - 169
  • [8] Synthesis and antituberculosis activity of C-phosphonate analogues of decaprenolphosphoarabinose, a key intermediate in the biosynthesis of mycobacterial arabinogalactan and lipoarabinomannan
    Centrone, CA
    Lowary, TL
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (25) : 8862 - 8870
  • [9] p-Cresyl 2,3-anhydro-5-deoxy-5-phthalimido-1-thio-α-D-lyxofuranoside
    Gallucci, JC
    Gadikota, RR
    Lowary, TL
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 : E365 - E365
  • [10] STRUCTURE OF 2,5/3,4-DIANHYDRO-D-ALTRITOL
    GARCIA, JG
    VOLL, RJ
    FRONCZEK, FR
    YOUNATHAN, ES
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 : 1692 - 1694