Synthesis and investigation of tetraphenyltetrabenzoporphyrins for electrocatalytic reduction of carbon dioxide

被引：8

作者：

Apaydin, Dogukan H. ^{[1
]}

Portenkirchner, Engelbert ^{[2
]}

Jintanalert, Pichayada ^{[3
]}

Strauss, Matthias ^{[1
]}

Luangchaiyaporn, Jirapong ^{[3
]}

Sariciftci, Niyazi Serdar ^{[1
]}

Thamyongkit, Patchanita ^{[4
]}

机构：

[1] Johannes Kepler Univ Linz, Inst Phys Chem, Linz Inst Organ Solar Cells LIOS, A-4040 Linz, Austria

[2] Univ Innsbruck, Inst Phys Chem, A-6020 Innsbruck, Austria

[3] Chulalongkorn Univ, Dept Chem, Fac Sci, Bangkok 10330, Thailand

[4] Chulalongkorn Univ, Res Grp Mat Clean Energy Prod STAR, Dept Chem, Fac Sci, Bangkok 10330, Thailand

来源：

SUSTAINABLE ENERGY & FUELS | 2018年 / 2卷 / 12期

关键词：

ELECTROCHEMICAL REDUCTION; PHOTOCHEMICAL REDUCTION; PORPHYRIN; CO2; COMPLEXES; ELECTRODE; ACID; IRON; BENZOPORPHYRIN; CONVERSION;

D O I：

10.1039/c8se00422f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the synthesis and electrochemical properties of freebase tetraphenyltetrabenzoporphyrin and its complexes of Zn(ii), Co(ii), Ni(ii), Cu(ii) and Sn(iv) towards electrochemical reduction of carbon dioxide (CO2). Based on cyclic voltammetry, it is shown that central metals significantly affect the electrocatalytic performance in the reduction of CO2 in terms of reduction potential and catalytic current enhancement. At an applied potential of -1.90 V vs. an Ag/AgCl quasi reference electrode for 20 h, the electrocatalytic reduction of CO2 realized by Zn(ii)- and Cu(ii)-tetraphenyltetrabenzoporphyrins to carbon monoxide resulted in faradaic efficiencies of around 48% and 33%, respectively.

引用

页码：2747 / 2753

页数：7

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