The syntheses, crystal, molecular and electronic structures of two polymorphs of [ReCl2(N2COPh)(C3N2H4)(PPh3)2] and [ReCl2(N2COPh)(py)(PPh3)2] complexes

被引：6
作者：
Dziegielewski, JO
Michalik, S
Kruszynski, R
Bartczak, TJ
Kusz, J
机构：
[1] Silesian Univ, Inst Chem, Dept Inorgan & Radiat Chem, PL-40006 Katowice, Poland
[2] Tech Univ Lodz, Inst Gen & Ecol Chem, Xray Crystallog Lab, PL-90924 Lodz, Poland
[3] Silesian Univ, Inst Phys, PL-40006 Katowice, Poland
来源：
POLYHEDRON | 2003年 / 22卷 / 25-26期
关键词：
rhenium; organodiazenido; X-ray structures; electronic structures;
D O I：
10.1016/j.poly.2003.07.010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The [ReCl2(eta(2)-NZCOPh-N',O)(PPh3)(2)] complex reacts with pyridine and pyrazole to give [ReCl2(N2COPh)(py)(PPh3)(2)] and [ReCl2(N2COPh)(C3N2H4)(PPh3)(2)], respectively. Two monoclinic polymers of [ReCl2(NZCOPh)(C3N2H4)(PPh3)(2)] and [ReCl2(N2COPh)(py)(PPh3)(2)] have been characterized by IR, UV-Vis, H-1 NMR, magnetic measurements and X-ray structure. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3307 / 3313
页数：7
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