ELECTROCHEMICAL STUDIES OF LEAD TELLURIDE BEHAVIOR IN ACIDIC NITRATE SOLUTIONS

被引:3
作者
Rudnik, E. [1 ]
Biskup, P. [2 ]
机构
[1] AGH Univ Sci & Technol, Fac Nonferrous Met, Dept Phys Chem & Met Nonferrous Met, PL-30059 Krakow, Poland
[2] Royal Grp, Abu Dhabi, U Arab Emirates
关键词
lead telluride; cyclic voltammetry; pH; nitric acid; THIN-FILMS; PBTE; ELECTRODEPOSITION; CHALCOGENIDES; AUTE2;
D O I
10.1515/amm-2015-0015
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Electrochemistry of lead telluride stationary electrode was studied in nitric acid solutions of pH 1.5-3.0. E-pH diagram for Pb-Te-H2O system was calculated. Results of cyclic voltammetry of Pb, Te and PbTe were discussed in correlation with thermodynamic predictions. Anodic dissolution of PbTe electrode at potential approx. -100 divided by 50 mV (SCE) resulted in tellurium formation, while above 300 mV TeO2 was mainly produced. The latter could dissolve to HTeO2+ under acidic electrolyte, but it was inhibited by increased pH of the bath.
引用
收藏
页码:95 / 100
页数:6
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