Highly stable core-shell Pt-CeO2 nanoparticles electrochemically deposited onto Fecralloy foam reactors for the catalytic oxidation of CO

被引：10

作者：

Cimino, S. ^{[1
]}

Lisi, L. ^{[1
]}

Totarella, G. ^{[1
]}

Barison, S. ^{[2
]}

Musiani, M. ^{[2
]}

Verlato, E. ^{[2
]}

机构：

[1] CNR, IRC, Ple V Tecchio 80, I-80125 Naples, Italy

[2] CNR, Ist Chim Mat Condensata & Tecnol Energia ICMATE, Corso Stati Uniti 4, I-35127 Padua, Italy

来源：

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2018年 / 66卷

关键词：

Structured catalysts; Cathodic deposition; Thermal stability; Environmental catalysts; HIGH-TEMPERATURE OXIDATION; ONE-POT SYNTHESIS; MONOLITHIC CATALYSTS; STRUCTURED CATALYSTS; PT/CEO2/C CATALYST; CERIA CATALYSTS; METHANE; PLATINUM; COMBUSTION; NANOCATALYSTS;

D O I：

10.1016/j.jiec.2018.06.007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The sequential electrodeposition of Pt nanoparticles and CeO2 protective layers has been explored as a simple method to prepare structured catalytic reactors characterized by a core-shell metal-metal oxide active phase directly anchored onto metallic (Fecralloy) 3D open foam substrates. The application of a CeO2 overlayer onto preformed Pt nanoparticles promoted the intrinsic catalytic activity for CO oxidation and induced a remarkable stabilization effect against sintering and extensive reconstruction of the active phase up to 800 degrees C. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

引用

页码：404 / 410

页数：7

共 52 条

[41] Catalytic properties of ceria and CeO2-containing materials [J].