Acyclic Diene Metathesis (ADMET) as Powerful Tool for Functional Polymers with Versatile Architectures

被引：7

作者：

Liu, Shuang ^{[1
,2
]}

Yan, Jing ^{[1
,2
]}

Zhang, Qiuyu ^{[2
]}

Yan, Yi ^{[1
,2
]}

机构：

[1] Northwestern Polytech Univ, Chongqing Technol Innovat Ctr, Chongqing 401135, Peoples R China

[2] Northwestern Polytech Univ, Sch Chem & Chem Engn, Dept Chem, Key Lab Special Funct & Smart Polymer Mat,Minist, Xian 710129, Peoples R China

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2022年 / 32卷 / 09期

基金：

美国国家科学基金会;

关键词：

Acyclic diene metathesis; Polymerization; Functional polymer; CONTROLLED/LIVING RADICAL POLYMERIZATION; II CHELATE POLYMER; ONE-POT SYNTHESIS; OLEFIN METATHESIS; PRECISION POLYMERS; CASTOR-OIL; COPOLYMERS; POLYETHYLENE; POLYOLEFINS; ACIDS;

D O I：

10.1007/s10904-022-02386-x

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Since the discovery of acyclic diene metathesis (ADMET), researchers have gradually developed ADMET polymerization into a mature methodology for the preparation of versatile polymers with various precise functional groups. As a representative stepwise polymerization method, ADMET enable the polymerization of relatively "inert" acyclic diene monomers. By rational design of monomer structures, the resulted functional materials can be used in various fields such as biomedicine, optoelectronics and stimulus responsive materials. This review will focus on the synthetic strategies of functional polymers with various precise moieties by ADMET over the past few decades, especially functional polyesters, polyethers, polyolefins, and conjugated polymers as well as organometallic polymers will be summarized. [GRAPHICS] .

引用

页码：3368 / 3394

页数：27