[N-(2-Hydroxyethyl)ethylenediamine-κ3N,N′,O]-cis-bis(isothiocyanato-κN)-copper(II)

被引：10

作者：

Pasaoglu, H ^{[1
]}

Karadag, A

Tezcan, F

Büyükgüngör, O

机构：

[1] Ondokuz Mayis Univ, Dept Phys, Fac Arts & Sci, TR-55139 Kurupelit, Turkey

[2] Gaziosmanpasa Univ, Dept Chem, Fac Arts & Sci, TR-60250 Tokat, Turkey

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷

关键词：

D O I：

10.1107/S0108270104033803

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the novel transition metal isothiocyanate complex of N-(2-hydroxyethyl)ethylenediamine (hydet-en) with copper, [Cu(NCS)(2)(C4H12N2O)], the Cu atom lies in a distorted square-pyramidal environment, coordinated by four N atoms in the basal plane and an apical O atom. The hydet-en ligand is N,N,O-tridentate, in contrast to the disposition in previously studied complexes, while the isothiocyanate ions act as N-atom donor ligands. The monomeric units are linked to one another by hydrogen bonds.

引用

页码：M93 / M94

页数：2

共 50 条

[31] CRYSTAL DATA AND OTHER PROPERTIES OF BIS(N-(2-HYDROXYETHYL)ETHYLENEDIAMINE)COPPER(2) NITRATE [J].

NASANEN, R ;

LEMMETTI, L ;

ILVONEN, P .

SUOMEN KEMISTILEHTI, 1968, 41 (04) :119-&

[32] POLAROGRAPHIC STUDIES OF CADMIUM(II) COMPLEXES WITH N,N'-BIS(2-HYDROXYETHYL)ETHYLENEDIAMINE-N,N'-DIACETIC ACID [J].

MATSUO, T ;

MASUDA, Y ;

SEKIDO, E .

NIPPON KAGAKU KAISHI, 1981, (08) :1265-1270

[33] Bis(ethylenediamine-κ2N,N′)bis-(phenytoinato-κN)cobalt(II) [J].

Hu, Xi-Lan ;

Xu, Xing-You ;

Wang, Da-Qi ;

Zhou, Yan-Qin .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 :M1470-U2038

[34] Synthesis of N-(2-hydroxyethyl)piperidines and N-(2-hydroxyethyl)perhydroquinolines [J].

N. G. Chernyshevskii Saratov State University, 410601 Saratov, Russia .

Chem. Heterocycl. Compd., 6 (745-746)

[35] Synthesis of N-(2-Hydroxyethyl)piperidines and N-(2-Hydroxyethyl)perhydroquinolines [J].

Golikov, A. G. ;

Reshetov, P. V. ;

Kriven'ko, A. P. .

Chemistry of Heterocyclic Compounds, 33 (06)

[36] BIS(N,N′-BIS(2-HYDROXYETHYL)ETHYLENEDIAMINE)NICKEL(II) SACCHARINATE: SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURE [J].

Karadogan, Alparslan ;

Karadag, Ahmet ;

Yilmaz, Veysel T. .

MACEDONIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING, 2015, 34 (01) :101-104

[37] Synthesis of N-(2-hydroxyethyl)piperidines and N-(2-hydroxyethyl)perhydroquinolines [J].

Golikov A.G. ;

Reshetov P.V. ;

Kriven'ko A.P. .

Chemistry of Heterocyclic Compounds, 1997, 33 (6) :745-746

[38] cis-Bis[N′-(4-bromobenzoyl)-N,N-dimethylthioureato-κ2O,S]copper(II) [J].

Binzet, Gun ;

Floerke, Ulrich ;

Kulcu, Nevzat ;

Arslan, Hakan .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 :M648-U1306

[39] SYNTHESES, PROPERTIES, AND CRYSTAL AND MOLECULAR-STRUCTURES OF BROMO[N,N-BIS(2-HYDROXYETHYL)GLYCINATO]COPPER(II) AND AQUABROMO[N,N-BIS(2-HYDROXYETHYL)GLYCINATO]COPPER(II) [J].

YAMAGUCHI, H ;

INOMATA, Y ;

TAKEUCHI, T .

INORGANICA CHIMICA ACTA, 1991, 181 (01) :31-36

[40] DFT studies of structural and some spectral parameters of copper(II) complexes with N,N,N′,N"-tetrakis (2-hydroxyethyl/propyl) ethylenediamine and tris(2-hydroxyethyl)amine [J].

Kumar, Rakesh ;

Obrai, Sangeeta ;

Mitra, Joyee ;

Sharma, Aparna .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2013, 115 :244-249

← 1 2 3 4 5 →